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Wolfgang Arlt, Friedrich-Alexander-Universität Erlangen-Nürnberg
Project: Modelling of the supported ionic-liquid-Phase (SILP) catalyst system
1. A. Buchele, W. Arlt; P1.16. Modeling of reactions in immobilized ionic liquids (SILP); Chemie Ingenieur Technik, 80(9), 1262, 2008
2. A. Buchele, W. Arlt; Modeling of Reactions with Immobilized Ionic Liquids (SILP); AICHE Annual Meeting 2008; Philadelphia, USA, November 15-21, 2008
3. A. Buchele, W. Arlt, M. Haumann, P. Wasserscheid; Modeling of the Supported Ionic Liquid Phase (SILP) Catalysis; 8th World Congress of Chemical Engineering (WCCE8); Montreal, Canada; August 23-27, 2009
4. Modeling of the Supported Ionic-Liquid-Phase (SILP) catalyst system. Poster(Bamberg, June 2007)
5. Modeling of the supported ionic-liquid-Phase(SILP) catalyst system. Invited talk (Bamberg, 2007)
Frank Bordusa, Martin-Luther-Universität Halle-Wittenberg
Project 1: Physicochemical characterisation of ionic liquids-mediated peptide acylation reactions
Project 2 (with Carmen Mrestani-Klaus): Impact of ionic liquids on the conformation of peptides and proteins
1. Ionic liquids-mediated peptide acylation reactions. Invited talk(Bamberg, June 2007)
2. N. Wehofsky, C. Wespe, V. Cerovsky, A. Pech, E. Hoess, R. Rudolph, and F. Bordusa, "Ionic Liquids and Proteases: A clean Alliance for Semisynthesis", ChemBioChem. 2008, DOI: 10.1002/cbic.200800025
3. Carmen Mrestani-Klaus, Annekathrin Richardt, Christian Wespe, Annegret Stark, Eberhard Humpfer and Frank Bordusa, "Basic applicability of HR-MAS NMR spectroscopy for structural studies of ionic liquid/peptide systems", submitted to the Journal of Physical Chemistry B, 28.5.2010, Manuscript ID: jp-2010-04848d.
4. C. Mrestani-Klaus, C. Wespe and F. Bordusa, Impact of ionic liquids on the conformation of peptides and proteins, DFG SPP 1191 Spring Meeting, Bamberg, 2009 (oral presentation)
5. A. Richardt, C. Mrestani-Klaus and F. Bordusa, Impact of ionic liquids (ILs) on the conformation of peptides and proteins probed by HR-MAS NMR spectroscopy, DFG SPP 1191 workshop; NMR Spectroscopy in Ionic Liquids;, Karlsruhe, 2009 (oral presentation)
6. C. Mrestani-Klaus, A. Richardt and F. Bordusa, Impact of ionic liquids on the conformation of peptides and proteins: a progress report, DFG SPP 1191 Zwischenkolloquium, Potsdam, 2009 (oral presentation)
7. A. Richardt, C. Mrestani-Klaus and F. Bordusa, Impact of ionic liquids on the conformation of peptides and proteins, DFG SPP 1191 Winter-School "Thermophysical Properties and Molecular Structure of Ionic Liquids&", Rostock, 2009 (oral presentation)
8. A. Richardt, C. Mrestani-Klaus and F. Bordusa, Impact of ionic liquids on the conformation of peptides studied by HR-MAS NMR spectroscopy, 31 European Peptide Symposium, Kopenhagen, 2010 (oral presentation)
Richard Buchner, Universität Regensburg
Project: Dielectric spectroscopy of the dynamics and association of ionic liquids mixed with polar compounds
1. S. Schrödle, G. Annat, D.R. MacFarlane, M. Forsyth, R. Buchner and G. Hefter, “Broadband dielectric response of the ionic liquid N-methyl-N-ethylpyrollidinium dicyanamide”, Chem. Commun. (2006) 1748-1750. DOI: 10.1039/b602209j
2. S. Schrödle, G. Annat, D.R. MacFarlane, M. Forsyth, R. Buchner* and G. Hefter, “High frequency dielectric response of the ionic liquid N-methyl-N-ethylpyrollidinium dicyanamide”, Aust. J. Chem. 60 (2007) 6-8. DOI: 10.1071/CH06251
3. A. Stoppa, J. Hunger, R. Buchner*, G. Hefter, A. Thoman and H. Helm, “Interactions and Dynamics in Ionic Liquids”, J. Phys. Chem. B 112 (2008) 4854-4858. DOI: 10.1021/jp800852z
4. J. Sangoro, C. Iacob, A. Serghei, S. Naumov, P. Galvosas, J. Kärger, C. Wespe, F. Bordusa, A. Stoppa, J. Hunger, R. Buchner and F. Kremer, “Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid”, J. Chem. Phys. 128(2008), 214509(5pp). DOI: 10.1063/1.2921796
5．C. Spickermann, J. Thar, S. B. C. Lehmann, S. Zahn, J. Hunger, R. Buchner,P.A. Hunt, T. Welton and B. Kirchner, Why are ionic liquids mainly associated In water? A Car-Parinello study of 1-ethyl-3-methyl-imidazolium chloride water mixture, J. Chem. Phys. 129 (2008) 104505 (1-13).DOI: 10.1063/1.2974098
6. J. Hunger, A. Stoppa, R. Buchner and G. Hefter, From Ionic Liquid to
Electrolyte Solution: Dynamics of Binary 1-N-Butyl-3-N-methylimidazolium
Tetrafluoroborate + Dichloromethane Mixtures, J. Phys. Chem. B 112 (2008)
12913-12919. DOI: 10.1021/jp8045627
7. C. Schröder, J. Hunger, A. Stoppa, R. Buchner and O. Steinhauser, On the
collective network of ionic liquid/water mixtures: II. Decomposition and interpretation of dielectric spectra, J. Chem. Phys. 129 (2008) 184501 (1-10).
DOI: 10.1063/1.3002563
8. A. Stoppa, J. Hunger and R. Buchner, Conductivities of binary mixtures of
ionic liquids with polar solvents, J. Chem. Eng. Data (R. Stokes Festschrift)
54 (2009) 472-479. DOI:10.1021/je800468h
9. J. Hunger, A. Stoppa, S. Schrödle, G. Hefter and R. Buchner, Temperature
dependence of the dielectric properties and dynamics of ionic liquids,
ChemPhysChem 10 (2009) 723-733. DOI: 10.1002/cphc.200800483
10. G. Hefter, R. Buchner, J. Hunger and A. Stoppa, Chemical Speciation in IonicLiquids and their Mixtures with Polar Solvents Using Dielectric Spectroscopy, in Ionic Liquids: From Knowledge to Application, Rogers, R. D.; Plechkova, N. V.; Seddon, K. R., Eds.; ACS Symposium Series; Ch. 4; American Chemical Society, Washington, 2009.
11. J. Hunger, A. Stoppa, R. Buchner and G. Hefter, Dipole Correlations in Ionic
Liquid 1-N-Ethyl-3-N-methylimidazolium Ethylsulfate and its Binary Mixtures with
Dichloromethane}, J. Phys. Chem. B 113 (2009) 9527-9537.DOI: 10.1021/jp9024574
12. D. A. Turton, J. Hunger, A. Stoppa, G. Hefter, A. Thoman, M. Walther, R. Buchner and K. Wynne, Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscale Aggregation, J. Am. Chem. Soc. 131 (2009) 11140-11146. DOI: 10.1021/ja903315v
13. G. Hefter, R. Buchner, J. Hunger and A. Stoppa, Chemical Speciation in Ionic Liquids and their Mixtures with Polar Solvents Using Dielectric Spectroscopy, in Ionic Liquids: From Knowledge to Application, Rogers R.D., Plechkov N.V., Seddon K.R., Eds., ACS Symposium Series Vol. 1030, Ch. 4 (pp. 61-74), American Chemical Society, Washington, 2010.
14. A. Stoppa, R. Buchner and G. Hefter, How ideal are binary mixtures of room-temperature ionic liquids?, J. Mol. Liq. 153 (2010) 46-51. DOI: 10.1016/j.molliq.2009.05.001
15. A. Stoppa, O. Zech., W. Kunz and R. Buchner, The conductivity of Imidazolium-based ionic liquids from (-35 to 195)
°C. A. Variation of Cation's Alkyl Chain, J. Chem. Eng. Data 55 (2010) 1768-1773. DOI: 10.1021/je900789j
16. O. Zech, A. Stoppa, R. Buchner and W. Kunz, he conductivity of Imidazolium-based ionic liquids from
(-35 to 195)C. B. Variation of the anion, J. Chem. Eng. Data 55 (2010) 1774-1778. DOI: 10.1021/je900793r
17. M. Bešter-Rogač,J. Hunger, A. Stoppa and R. Buchner, Molar Conductivities and association constants of 1-Butyl-3-Methylimidazolium Chloride and 1-Butyl-3-Methylimidazolium Tetrafluoroborate in methanol and DMSO, J. Chem. Eng. Data 55 (2010) 1799-1803. DOI: 10.1021/je900531b
18. K. Wynne, D. Turton, J. Hunger, A. Stoppa, G. Hefter, A.
Thoman, M. Walther and R. Buchner, Terahertz dynamics of ionic liquids from a combined dielectric relaxation, terahertz, and optical Kerr effect study: evidence for mesoscopic aggregation, Proc. SPIE 7601 (2010) 76010H/1-10.
Robert Berger, TU Darmstadt - Luigi Delle Site, MPI fuer Polymerforschung - Christian Holm, Universitaet Stuttgart
Project: Multiscale simulations on the structure and dynamics of ionic liquids
1. B. Qiao, C. Krekeler, R. Berger, L. Delle Site, C. Holm, Effect of anions on static orientational correlations, hydrogen bonds, and dynamics in ionic liquids: a simulation study, J. Phys. Chem. B 112, 1743 (2008)
2. C. Krekeler, Y. Zhao, J. Schmidt, B. Qiao, R. Berger, C. Holm, L. Delle Site, Study of 1,3-dimethylimidazolium chloride with electronic structure methods and force fields approaches, J. Chem. Phys. 129, 174503 (2008)
3. F. Dommert, J. Schmidt, B. Qiao, C. Krekeler, Y. Zhao, R. Berger, L. Delle Site, C. Holm, A comparative study of two classical force fields on statics and dynamics of [EMIM] [BF4] via molecular dynamics simulations, J. Chem. Phys 129, 224501 (2008)
4. F. Dommert, J. Schmidt, C. Krekeler, Y. Zhao, R. Berger, L. Delle Site,
Christian Holm, Towards multiscale modeling of ionic liquids: From
electronic structure to bulk properties, J. Mol. Liq. 152, 2-4 (2010)
5. C. Krekeler, F. Dommert, J. Schmidt, Y. Zhao, C. Holm, R. Berger, L. Delle Site, Electrostatic properties of liquid 1,3-dimethylimidazolium chloride: role of polarization and effect of the bulk, Phys. Chem. Chem. Phys. 12,1817-1821 (2010)
6. J. Schmidt, C. Krekeler, F. Dommert, Y. Zhao, R. Berger, L. Delle Site, C. Holm, Ionic charge reduction and atomic partial charges from first-principles calculations of 1,3-dimethylimidazolium chloride, J. Phys. Chem. B 114, 6150-6155 (2010)
Andreas Bund, Technische Universität Dresden
Project: STM and QCM investigation of refractory metal electrodeposition in ionic liquids: influence of the ionic liquid on the electroreduction processes of the respective refractory metal halides
1. F. Endres, S. Zein El Abedin, A.Y. Saad, E.M. Moustafa, N. Borissenko, W.E. Price, G.G. Wallace, D.R. MacFarlane, P.J. Newman, A. Bund: On the
electrodeposition of titanium in ionic liquids. Phys. Chem. Chem. Phys. 10 (2008) 2189-2199.
2. E. M. Moustafa, E. Zschippang, A. Shkurankov, A. Moursi, A. Bund, S. Zein El Abedin, F. Endres: "Electrodeposition of Al in 1-butyl-1-methylpyrrolidinium bis(trifluoromethyl-sulfonyl) amide and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) amide ionic liquids: In situ STM and EQCM studies". J. Phys. Chem. B 111 (2007) 4693-4704.
3. A. Bund, E. Zschippang: Nickel Electrodeposition from a Room Temperature Eutectic Melt. ECS Transactions Vol. 3, Issue 35 (Molten Salts 15, in Memory of Robert Osteryoung), 2007, pp. 253-261.
Frank Endres, Technische Universität Clausthal
Project 1: STM and QCM investigation of refractory metal electrodeposition
in ionic liquids: influence of the ionic liquid on the electroreduction processes
of the respective refractory metal halides
Project 2: Interfaces between ionic liquids and low temperature plasmas - A novel type of fluid/fluid interface
1. Plasma-Electrochemical Deposition of Nanoscale Metals and Semiconductors in Ionic Liquids, S. A. Meiss, M. Rohnke, L. Kienle, S. Z. El Abedin, F. Endres, and J. Janek, ChemPhysChem. 8 (2007) 50-53
2. Ionic liquids as green electrolytes for electrodeposition of nanomaterials, S. Zein El Abedin, M. Pölleth, S. A. Meiss, J. Janek, F. Endres, Green Chemistry 9(6) (2007) 549-553
3. F. Endres, S. Zein El Abedin, A.Y. Saad, E.M. Moustafa, N. Borissenko, W.E. Price, G.G. Wallace, D.R. MacFarlane, P.J. Newman, A. Bund: On the electrodeposition of titanium in ionic liquids. Phys. Chem. Chem. Phys. 10 (2008) 2189-2199.
4. Studies on the Electrodeposition of Tantalum in 1-butyl-1-methylpyrrolidinium bis(trufluoromethylsulfonyl)amide Ionic Liquid. Poster(Bamberg, June 2007)
5. Studies on the Electrodeposition of Tantalum in 1-butyl-1-methylpyrrolidinium bis(trufluoromethylsulfonyl)amide Ionic Liquid. Invited talk(Bamberg, June 2007)
6. A time-of-flight secondary ion mass spectroscopy of the 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide RT ionic liquid, J. Guenster, O. Hoefft, S. Krischok, R. Souda, Surface Science 602 (2008) 3403.
7. Plasma Electrochemistry in ionic liquids: deposition of copper nanoparticles, M. Brettholle, O. Hoefft, L. Klarhoefer, S. Mathes, W. Maus-Friedrichs, S. Zein El Abedin, S. Krischok, J. Janek and F. Endres, Phys. Chem. Chem. Phys. 12 (2010) 1724.
8. Surface electronic structure of imidazolium based ionic liquids studied by electron spectroscopy, T. Ikari, A. Keppler, M. Reinmoeller, W.J.D. Beenken, S. Krischok, M. Marschewski, W. Maus Friedrichs, O. Hoefft and F. Endres, e-Journal of Surface Science and Nanotechnology 8 (2010) 241.
9. Unexpected decomposition of the bis(trifluoromethylsulfonyl) amide anion during electrochemical copper oxidation in an ionic liquid, A.S. Ismail, S. Zein el Abedin, O. Hoefft, and F. Endres, Electrochem. Comm. (2010), doi:10.1016/j.elecom.2010.04.018
10. Plasma electrochemistry in 1-butyl-3-methylimidazolium dicyanamide: copper nanoparticles from CuCl and CuCl2, N. Kulbe, O. Hoefft, A. Keppler, S. Zein El Abedin, S. Krischok, J. Janek and F. Endres, submitted to Plasma Processes and Polymers.
Andreas Paul Fröba, SAOT Erlangen
Project: Characterization of the Nature of Interaction in Ionic Liquid Co-solvent mixtures by Dynamic Light Scattering (DLS)
1. Fröba, A. P. and Leipertz, A., 2010, “Characterization of Ionic Liquids and Their Mixtures with Co-Solvents by Dynamic Light Scattering (DLS),” Proc. 9th Asian Thermophysical Properties Conference, October 19-22, 2010, Beijing, China
2. Lehmann, J., Rausch, M. H., Leipertz, A., and Fröba, A. P., 2010, “Densities and Excess Molar Volumes for Binary Mixtures of Ionic Liquid 1-Ethyl 3-methylimidazolium Ethylsulfate with Co-solvents,” accepted for publication in J. Chem. Eng. Data.
3. Hasse, B., Lehmann, J., Assenbaum, D., Wasserscheid, P., Leipertz, A., and Fröba, A. P., 2009, “Viscosity, Interfacial Tension, Density, and Refractive Index of Ionic Liquids [EMIM][MeSO3], [EMIM][MeOHPO2], [EMIM][OcSO4], and [BBIM [NTf2] in Dependence on Temperature at Atmospheric Pressure,” J. Chem. Eng. Data, Vol. 54, pp. 2576-2583.
4. Fröba, A. P., Kremer, H., and Leipertz, A., 2008, “Density, Refractive Index, Interfacial Tension, and Viscosity of Ionic Liquids [EMIM][EtSO4], [EMIM][NTf2], [EMIM][N(CN)2], and [OMA][NTf2] in Dependence on Temperature at Atmospheric Pressure,” J. Phys. Chem. B, Vol. 112, pp. 12420-12430.
5. Fröba, A. P., Wasserscheid, P., Gerhard, D., Kremer, H., and Leipertz, A, 2007, “Revealing the Influence of the Strength of Coulomb Interactions on the Viscosity and Interfacial Tension of Ionic Liquid Cosolvent Mixtures,” J. Phys. Chem. B, Vol. 111, pp. 12817-12822.
6. Kolbeck, C., Lehmann, J., Lovelock, K. R. J., Cremer, T., Paape, N., Wasserscheid, P., Maier, F., Steinrück, H.-P., and Fröba, A. P, 2010, “On the Density and Surface Tension of Ionic Liquids,” submitted for publication in J. Phys. Chem. B.
7. Fröba, A. P., Rausch, M. H., Lehmann, J., and Leipertz, A., 2010, “Mutual Diffusion in Ionic Liquid Co-solvent Mixtures by Dynamic Light Scattering (DLS),” submitted for publication in J. Phys. Chem. B.
8. Fröba, A. P, Krzeminski, K., Rausch, M. H., and Leipertz, A., 2010, “Thermal Conductivity of Ionic Liquids – Measurement and Prediction,” submitted for publication in Int. J. Thermophys.
Heiner J. Gores, Universität Regensburg
Project: Synthesis, Stability and Electrochemical Characterization of New Ionic Liquids Based on Asymmetrical Borates
1. T. Herzig, C. Schreiner, H. Bruglachner, S. Jordan, M. Schmidt, H. J. Gores, "Temperature and Concentration Dependence of Conductivities of Some New Semi-chelatoborates in Acetonitrile and Comparison with other Borates", J. Chem. Eng. Data, 53, 434 (2008).
2. T. Herzig, C. Schreiner, D. Gerhard, P. Wasserscheid, H. J. Gores, "A new Class of Ionic Liquids based on Asymmetric Difluoroborates with Bidentate Ligands", J. Fluorine Chem., 128, 612-618 (2007).
3. P. Wachter, H-G. Schweiger, F. Wudy, H.J. Gores, "Efficient determination of crystallisation and melting points at low cooling and heating rates with novel computer controlled equipment", J. Chem. Thermodynamics (2008), doi: 10.1016/j.jct.2008.05.012
4. F. Wudy, M. Multerer, C. Stock, G. Schmeer, H.-J. Gores, "Rapid impedance scanning QCM for electrochemical applications based on miniaturized hardware and high-performance curve fitting", Electrochimica Acta (2007), doi: 10.1016/j.electacta.2008.04.079
5. C. Schreiner, T. Herzig, H. J. Gores, "Verfahren zur Darstellung von ionischen Verbindungen mit den Anionen MFm-eEe¯, MFm-2gGg¯ oder MFm-e-2gEeGg¯", Patent in application (Number: DE102007050700.5)
6. Synthesis, Stablity and Electrochemical Characterisation of Ionic Liquids based on Asymmetric Borates. Invited talk(Bamberg, June 2007)
7. Electrochemical Investigation of Ionic Liquids. Ionics, Electrodics, Application. Invited talk(Bamberg, June 2007)
8. C. Schreiner, "Reference Electrodes for Electrochemical Measurements". Talk on Winter School (Leipzig Feb. 2008).
9. C. Schreiner, H. J. Gores, "Synthesis, Stability and Electrochemical Characterisation of New Ionic Liquids based on Mixed Borates", Poster (Bamberg, Dec. 2007).
Ralf Giernoth Universität Koeln
Project: In situ NMR spectroscopy in ionic liquids for the investigation of solvent-solute and ionic interactions
1. "Transition-metal free synthesis of perdeuterated imidazolium ionic liquids
byalkylation and H/D exchange":R. Giernoth, D. Bankmann, Eur. J. Org. Chem.
2008, 2881-2886.
2. "Nuclear Magnetic Resonance Spectroscopy in Ionic Liquids": R. Giernoth, in: "Ionic Liquids in Chemical Analysis" (Hrsg.: M.\ Koel), CRC Press/Taylor & Francis Books, Boca Raton FL (USA), 2008, 355-370.
3. "BINBAM - A New Motif for Strong and Chiral Brønsted Acids": M. Treskow, J.
Neudörfl, R. Giernoth, Eur. J. Org. Chem. 2009, 25, 3693-3697.
4. "NMR spectroscopy in ionic liquids", R. Giernoth, Top. Curr. Chem. 2009, 290, 263-283.
5. "Ionische Flüssigkeiten für Spezialaufgaben -- von der Katalyse bis zur
Analytik", R. Giernoth, Angew. Chem. 2010, 122, 2896-2901.
5b. "Task-specific ionic liquids", R. Giernoth, Angew. Chem. Int. Ed. 2010, 49, 2834-2839. (Publications 5 and 5b are identical, but written in German and English, respectively)
Andreas Heintz, Universität Rostock
Project: The study of the vapor pressure and the heat of vaporization of ionic liquids
1. Dz.H. Zaitsau, V.N. Emel’yanenko, S.P. Verevkin, A. Heintz "Imdazolium Based Ionic Liquids. 1-Ethyl-3-methylimidazolium Thiocyanate: Rotating-Bomb Combustion Calorimetry and First-Principles Calculations" PCCP., (2010), submitted.
2. V.N. Emel’yanenko, Dz.H. Zaitsau, S.P. Verevkin, A. Heintz "Imidazolium Based Ionic Liquids. 1-Ethanol-3-Methyl-Pyridinium Dicyanoamide: Thermochemical Measurement and First-Principles Calculations" PCCP., (2010), submitted
3. S.P. Verevkin, V.N. Emel’yanenko, Dz.H. Zaitsau, A. Heintz, C.D. Muzny, M.L. Frenkel "Are the Group Contribution Methods Applicable to Ionic Liquids?" Phys. Chem. Chem. Phys., (2010), submitted
4. R. Ludwig, K. Fumino, S.P. Verevkin, A. Heintz "Estimating enthalpies of vaporization of imidazolium-based ionic liquids from far infrared measurements" Phys. Chem. Chem. Phys., (2010), accepted
5. T. Peppel, M. Köckerling, M. Geppert-Rybczynska, R.V. Rallys, J.K. Lehmann, S.P. Verevkin, A. Heintz "Niedrigviskose paramagnetische Ionische Flüssigkeiten mit zweifachnegativ geladenen [CoII(NCS)4]2–Ionen" Angew. Chem., (2010), submitted
6. A. Heintz, M. Geppert-Rybczynska "Densities and Excess Volumes of Ionic Liquid Mixtures" J. Chem. Eng. Data, (2010), submitted
7. A. Heintz, J.K. Lehmann, S. Kozlova, A.B. Bazyleva, D. Ondo "Calorimetric Study of the Miccellation Process of Ionic Liquids in Aqueous Solutions "Fluid Phase Eq., (2010), in press
8. A. Heintz, R. Ludwig, E. Schmidt "Limiting Diffusion Coefficients of Ionic Liquids in Water and Methanol: A Combined Experimental and Molecular Dynamics Study"
Phys. Chem. Chem. Phys., (2010), submitted
9. M. Geppert-Rybczynska, J.K. Lehmann, J. Safarov, A. Heintz "Surface excess data of Mixtures of Ionic Liquids with Water and Ethanol based on surface tension and vapor pressure measurements" J. Chem. Thermodyn., (2010), submitted
10. V. N. Emel’yanenko, S. P. Verevkin, A. Heintz "Pyridinium Based Ionic Liquids. n-Butyl-3-Methyl-Pyridinium Dicyanoamide: Thermochemical Measurement and First-Principles Calculations" PCCP, (2010) submitted
11. S.P. Verevkin, V.N. Emel’yanenko, E. Hopmann, W. Arlt "Thermochemistry of Ionic Liquid-Catalysed Reactions. Isomerisation and Transalkylation of tert-Alkyl-Benzenes. Are these systems ideal?" J. Chem. Thermodyn., 42,(2010) in press
12. S. P. Verevkin, V. N. Emel’yanenko, A.V. Toktonov, P. Goodrich, C. Hardacre "Thermochemistry of Ionic Liquid-Catalysed Reactions. Theoretical and Experimental Study of the Beckmann Rearrangement – Kinetic or Thermodynamic Control?" Ind. Eng. Chem. Res., 48, 9809-9816 (2009)
13. S.P. Verevkin, V.N. Emel’yanenko, E.N. Stepurko, R.V. Ralys, D.H. Zaitsau, A. Stark "Biomass-derived platform chemicals: Thermodynamic studies on the conversion of 5-hydroxymethylfurfural into bulk intermediates" Ind. Eng. Chem. Res., 48, 10087–10093 (2009)
14. V.N. Emel’yanenko, S.P. Verevkin, A. Heintz, K. Voß, A. Schulz "Imidazolium Based Ionic Liquids. 1-Methyl Imidazolium Nitrate: Thermochemical Measurement, Mass Spectrometry and ab initio Calculations" J. Phys. Chem. B , 113, 9871-9876 (2009)
15. S. P. Verevkin, V. N. Emel’yanenko, A.V. Toktonov, P. Goodrich, C. Hardacre "Thermochemistry of Ionic Liquid Catalyzed Reactions. Experimental and Theoretical Study of Chemical Equilibria of Izomerization and Transalkylation of tert-Amylbenzenes" J. Phys. Chem. B, 113, 12704-12710 (2009)
16. S.A. Kozlova, S.P. Verevkin, A. Heintz, T. Peppel, M. Köckerling "Activity Coefficients at Infinite Dilution of Hydrocarbons, Alkylbenzenes, and Alcohols in the Paramagnetic Ionic Liquid 1-Butyl-3-Methyl-Imidazolium Tetrachloridoferrate(III) Using Gas-Liquid Chromatography" J. Chem. Thermodyn., 41, 330-333 (2009)
17. S.A. Kozlova, S.P. Verevkin, A. Heintz, T. Peppel, M. Köckerling "Paramagnetic Ionic Liquid 1-Butyl-3-methylimidazoliumTetrabromidocobaltate(II): Activity Coefficients at Infinite Dilution of OrganicSolutes and Crystal Structure" J. Chem. Eng. Data, 54,1524-1528 (2009)
18. K.N. Marsh, J.F. Brennecke, R.D. Chirico, M. Frenkel, A. Heintz, J.W. Magee, C.J. Peters, L.P. Rebelo, K.R. Seddon "Thermodynamic and Thermophysical Properties of the Reference Ionic Liquid: 1-Hexyl-3-Methylimidazolium bis(trifluoromethyl)sulfonylamide Including Mixtures. Part I. Experimental Methods and Results" Pure and Applied Chem., 31, 781-790 (2009)
19. A. Heintz, J.K. Lehmann, E. Schmidt, A. Wandschneider "Diffusion Coefficients of Imidazolium Based Ionic Liquids in Aqueous Solutions" J. Sol. Chem., 38, 1079-1083 (2009)
20. S.P. Verevkin, "Ionic Liquids. How to Get Enthalpy of Vaporization Predicted? Simple Rule for this Complex Property" Angew. Chem. Int. Ed., 47, 5071-5074 (2008)
21. S. P. Verevkin, S. A. Kozlova, V. N. Emel’yanenko, P. Goodrich, C. Hardacre "Thermochemistry of Ionic Liquid-Catalysed Reactions. Experimental and Theoretical Study of Chemical Equilibria of Isomerisation and Transalkylation of tert-Butyl-Benzenes" J. Phys. Chem. A, 112, 11273-11282 (2008)
22. V. N. Emel’yanenko, S. P. Verevkin, A. Heintz, C. Schick "Ionic Liquids. Combination of combustion calorimetry with the high-level quantum chemical calculations for deriving vaporisation enthalpies" J. Phys. Chem. A, 112, 8095-8098 (2008)
23. V.N. Emel’yanenko, S.P. Verevkin, A. Heintz, J.-A. Corfield, A. Deyko, K. R.J. Lovelock, P. Licence, R.G. Jones "Pyrrolidinium Based Ionic Liquids. 1-Butyl-1-Methyl Pyrrolidinium Dicyanoamide: Thermochemical Measurement, Mass Spectrometry and ab initio Calculations" J. Phys. Chem. B,112, 11734–11742 (2008)
24. Heintz, J.K. Lehmann, A. Wandschneider "Surface Tension measurements of Pure Ionic Liquids and Binary Mixtures Containing Ionic Liquids Including Excess Volumes" J. Chem. Eng. Data, 53, 596–599 (2008)
25. M.P. Shevelyova, Dz.H. Zaitsau, Y.U. Paulechka, A.V. Blokhin, G.J. Kabo, S.P. Verevkin, A. Heintz "Solid-Liquid Equilibrium and Activity Coefficients for Caprolactam+1-Hexyl-3-Methylimidazoium bis(Trifluoro-methylsul-fonyl)imide and Cyclohexanone oxime+1-Hexyl-3-Methylimidazoium bis(trifluoromethyl-sulfonyl)imide Binaries. J. Chem. Eng. Data, 52, 1360-1365 (2007)
26. V.N. Emel’yanenko, S.P. Verevkin, A. Heintz "The Gaseous Enthalpy of Formation of the Ionic Liquid 1-Butyl-3-Methyl-imidazolium Dicyanoamide from Combustion Calorimetry, Vapor Pressure Measurements, and ab initio Calculations" J. Am. Chem. Soc., 129, 3930 – 3937 (2007)
27. Heintz, J. K. Lehmann, A. Tschersich, Ch. Wertz “Liquid-Liquid Equilibria and Liquid-Liquid Interfacial Tension Measurement of Mixtures Containing Ionic Liquids" J. Mol. Liquids, 131/132, 2 – 6 (2007)
28. Wulf, T. Köddermann, Ch. Wertz, A. Heintz, R. Ludwig "Water Vibrational Bands as a Polarity Parameter for Ionic Liquids" Z. Phys. Chem. , 220, 1361 – 1376 (2006)
29. Heintz, S.P. Verevkin, J.K. Lehmann, T.V. Vasiltsova, D. Ondo "Activity Coefficients at Infinite Dilution and Enthalpies of Solution of Methanol, 1-Butanol, and 1-Hexanol in 1-Methyl-3-Hexyl-Imidazolium Bis(trifluoromethylsulfonyl)Imide" J. Chem. Thermodyn., 39, 268 – 274 (2006)
30. E. Balantseva, J.K. Lehmann, A. Heintz "Enthalpies of Solution of Organic Solutes in the Ionic Liquids [Me3BuN][NTf2] and [EMIM][EtSO4]" Z. Phys. Chem., 220, 1499 – 1505 (2006)
31. Dz. H. Zaitsau, G.J. Kabo, A.A. Strechan, Y.U. Paulechka, A. Tschersich, S.P. Verevkin, A.Heintz "Experimental Vapor Pressure of 1-Alkyl-3-Methyl-Imidazolium bis(Trifluoromethanesulfonyl)imides and a Correlation Scheme for Estimation of Vaporization Enthalpies of Ionic Liquids“ J. Phys. Chem. A, 110, 7303 – 7306 (2006)
32. I.A. Sumartschenkova, S.P. Verevkin, T.V. Vasiltsova, E. Bich, A. Heintz, M.P. Shevelyova, G.J. Kabo “Experimental Study of Thermodynamic Properties of Mixtures Containing the Ionic Liquid 1-Ethyl-3-Methyl-Imidazolium Ethyl Sulfate Using Gas-Liquid Chromatography and Transpiration Method" J. Chem. Eng. Data, 52, 2138 – 2144 (2006)
33. T. Köddermann, Ch. Wertz, A. Heintz, R. Ludwig “The Association of Water in Ionic Liquids and How it can be Used as a Reliable Measure for Polarity" Angew. Chem. Int. Ed., 45, 3697 - 3702 (2006)
34. T. Köddermann, Ch. Wertz, A. Heintz, R. Ludwig “Ion-Pair Formation of the Ionic Liquid 1-Ethyl-3-methylimidazolium bis(triflyl)imide as Function of Temperature and Concentration" Chem. Phys. Chem., 7, 1944 – 1949 (2006)
35. Heintz, Ch. Wertz “Ionic Liquids - A Most Promising Research Field in Solution Chemistry and Thermodynamics" Pure Appl. Chem., 78, 1587 - 1593 (2006)
36. Heintz, T.V. Vasiltsova, J. Safarov, E. Bich, S. P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 9. Activity coefficients at Infinite Dilution of Hydrocarbons, Alcohols, Esters and Aldehydes in Tri-Methyl-Butyl-Ammonium Bis-(trifluoromethylsulfonyl)Imide Using Gas Liquid Chromatography and Static Vapor Pressure Method" J. Chem. Eng. Data, 51(2), 648 - 655 (2006)
37. Heintz, S.P. Verevkin, D. Ondo “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 8. Activity Coefficients at Infinite Dilution of Hydrocarbons, Alcohols, Esters, and Aldehydes in 1-Methyl-3-Hexyl-Imidazolium Bis(trifluoromethyl-sulfonyl)Imide Using Gas Liquid Chromatography" J. Chem. Eng. Data, 51, 434 - 437 (2006)
38. T.V. Vasiltsova, S.P. Verevkin, E. Bich, A. Heintz, R. Bogel-Lukasik, U. Domanska “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 7. Activity Coefficients of Aliphatic and Aromatic Esters, and Benzylamine in 1-Methyl-3-Ethyl-Imidazolium Bis(trifluoromethyl-sulfonyl)Imide Using the Transpiration Method" J. Chem. Eng. Data, 51, 213 - 218 (2006)
39. J. Safarov, S. P. Verevkin, E. Bich, P. Wasserscheid, A. Heintz "Vapor Pressures and Activity Coefficients of n-Alcohols and Benzene in Binary Mixtures with 1-Methyl-3-Butyl-Imidazolium Octylsulfate and 1-Methyl-3-Octyl-Imidazolium Tetrafluoroborate" J. Chem. Eng. Data, 51, 518 - 525 (2006)
40. A. Heintz, S.P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 6. Activity Coefficients at Infinite Dilution. Esters, and Aldehydes in [OMIM][NTf2] Using Gas-Liquid Chromatography" J. Chem. Eng. Data, 50, 1515 - 1519 (2005)
41. Heintz, L. Martinez Casás, I.A. Nesterov, V.N. Emel'yanenko, S.P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 5. Activity Coefficients at Infinite Dilution. Esters, and Aldehydes in [BMIM][NTf2] Using Gas-Liquid Chromatography" J. Chem. Eng. Data, 50, 1510 - 1514 (2005)
42. Heintz “Recent Developments in Thermodynamics and Thermophysics of Non-aqueous Fluid Mixtures Containing Ionic Liquids. A Review" J. Chem. Thermodyn., 37, 525 - 535 (2005)
43. J. Safarov, S.P. Verevkin, E. Bich, E. Hassel, A. Heintz “Thermodynamic Properties of Mixtures Containing Ionic Liquids. Vapor Pressures and Activity Coefficients of n-Alcohols and Benzene in Binary Mixtures with 1-Methyl-3-Butyl-Imidazolium Bis(trifluoromethyl-sulfonyl)Imide" Fluid Phase Eq., 236, 222 - 228 (2005)
44. Heintz, J. K. Lehmann, Chr. Wertz, J. Jacquemin “Liquid-Liquid Equilibria of Binary Mixtures of [C2MIM][NTf2] with Propan-1-ol, Butan-1-ol, and Pentan-1-ol, and [C4MIM][NTf2] with Cyclohexanol and 1,2-Hexanediol Including Studies of the Influence of Water" J. Chem. Eng. Data, 50(3), 956 - 960 (2005)
45. Heintz, D. Klasen, J.K. Lehmann, Chr. Wertz "Excess Molar Volumens and Liquid-Liquid Equilibria of the Ionic Liquid 1-Methyl-3-octyl-imidazolium-tetrafluoroborate Mixed with Butan-1-ol and Pentan-1-ol" J. Sol. Chemistry, 34, 1135 - 1144 (2005)
46. T.V. Vasiltsova, S.P. Verevkin, E. Bich, R. Lukasik, U. Domanska, A. Heintz "Thermodynamic Properties of Mixtures Containing Ionic Liquids. Activity Coefficients of Ethers and Alcohols in 1-Methyl-3-Ethyl-Imidazolium bis(trifluoromethyl-sulfonyl)Imide Using the Transpiration Method" J. Chem. Eng. Data, 50, 141 - 148 (2005)
47. E. Bich, T. V. Vasiltsova, S. P. Verevkin, A. Heintz “Activity Coefficients of Aldehydes and Ketones in Mixtures with the Ionic Liquids 1-Methyl-3-Ethyl-Imidazolium Bis(trifluoromethyl-sulfonyl)Imide Using the Transpiration Method" Fluid Phase Eq., 218, 165 - 175 (2004)
48. Heintz, W. Marczak, S.P. Verevkin “Activity Coefficients and Heats of Dilution in Mixtures Containing Ionic Liquids" Chapter 14 in “Ionic Liquids. Fundamentals, Challenges, and Opportunities" ed. by R. D. Rogers and K. R. Seddon ACS Symposium Series No. 901, (2004)
49. Heintz, W. Marczak “Enthalpies of Solution of Organic Solutes in the Ionic Liquid 1-methyl-3-ethyl-imidazolium bis-(trifluoromethylsulfonyl)amide" J. Sol. Chem. , 32, 519 - 526 (2003)
50. Heintz, J. K. Lehmann, C. Wertz “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 3. Liquid-Liquid Equilibria of Binary Mixtures of 1-Ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide with Propan-1-ol, Butan-1-ol, and Pentan-1-ol" J. Chem. Eng. Data, 48, 472 - 474 (2003)
51. Heintz, J.K. Lehmann, S.P. Verevkin "Thermodynamic Properties of Liquid Mixtures Containing Ionic Liquids" Chapter 12 in “Ionic Liquids as Green Solvents. Progress and Prospects" edited by R. Rogers and K. R. Seddon ACS Symposium Series No. 856 (2003)
52. Heintz, D. Klasen, J. K. Lehmann “Excess Molar Volumes and Viscosities of Binary Mixtures of the Ionic Liquid 4-Methyl-N-butyl-pyridinium-tetrafluoroborate with Methanol at 298.15 K, 313.15 K, 323.15 K and Atmospheric Pressure" J. Sol. Chem., 31, 467 - 476 (2002)
53. Heintz, D.V. Kulikov, S.P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 2. Activity Coefficients at Infinite Dilution of Hydrocarbons and Polar Solutes in 1-Methyl-3-ethyl-imidazolium Bis(trifluoromethyl-sulfonyl)amide and in 1,2-Dimethyl-3-ethyl-imidazolium Bis(trifluoromethyl-sulfonyl)amide Using Gas-Liquid Chromatography" J. Chem. Eng. Data, 47, 894-899 (2003)
54. Heintz, D.V. Kulikov, S.P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. Activity Coefficients at Infinite Dilution of Polar Solutes in 4-Methyl-n-Butyl-Pyridinium Tetrafluoroborate Using Gas-Liquid Chromatography" J. Chem. Thermodyn., 34, 1341-1347 (2002)
55. Heintz, D.V. Kulikov, S.P. Verevkin “Thermodynamic Properties of Mixtures Containing Ionic Liquids. 1. Activity Coefficients at Infinite Dilution of Alkanes, Alkenes, and Alkylbenzenes in 4-Methyl-n-butylpyridinium Tetrafluoroborate Using Gas-Liquid Chromatography" J. Chem. Eng. Data, 46, 1526-1529 (2001)
Conference Contributions:
1. S.P. Verevkin, A. Heintz, J. Safarov, W. Marczak. Activity Coefficients and Heats of Dilution of Organic Solvents in Ionic Liquids 1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg, Austria
2. A. Heintz, S. P. Verevkin, J. Safarov, E. Bich THERMODYNAMIC PROPERTIES OF MIXTURES CONTAINING IONIC LIQUIDS 1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg, Austria
3. S. P. Verevkin,. J. K. Lehmann. J. Safarov, A. Heintz Neue thermodynamische Messergebnisse und Konsistenztests an Mischungen mit ionischen Flüssigkeiten GVC-Fachausschuß“ Thermodynamik“ und VDI-GET „Thermodynamik-Kolloquium“ 6./7. Oktober 2005 in Frankfurt/Main.
4. S. P. Verevkin, V.N. Emel’yanenko THERMODYNAMIC PROPERTIES OF THE GREEN SOLVENTS. THERMOINTERNATIONAl-2006, 30.7/4.8 2006, University of Colorado, Boulder, USA.
5. Dz.H. Zaitsau, G.J. Kabo, Y.U. Paulechka, A. Heintz, S.P. Verevkin THE VAPOR PRESSURE FOR 1-ALKYL-3-METHYLIMIDAZOLIUM- bis- (TRIFLUORO-METHANE-SULFONYL)IMIDES THERMOINTERNATIONAl-2006, 30.7/4.8 2006, University of Colorado, Boulder, USA.
6. S. P. Verevkin, V. N. Emel’yanenko, A. Heintz Quantitative Messungen der Dampfdrücke von ionischen Flüssigkeiten mit Hilfe der Transpirationsmethode und Vergleich mit der Knudse-Zell-Methode. GVC-Fachausschuß“ Thermodynamik“ und VDI-GET „Thermodynamik-Kolloquium“ 5. /6. Oktober 2006, Universität Dortmund.
7. Sergey P. Verevkin, Vladimir N. Emel’yanenko, Andreas Heintz Gaseous Enthalpy of Formation of the Ionic Liquids from Combustion Calorimetry, Vapor Pressure Measurements, and Ab Initio Calculations „COIL-2“ Yokohama, 5-10 August 2007, Japan.
8. Andreas Heintz, Jochen K. Lehmann, Sergey P. Verevkin, Svetlana A. Kozlova Calorimetric Study of the Micellation Process of [C16MIM]Cl and [C16MIM]BF4 in Aqueous Solution and in Ethylammoniumnitrate. „COIL-2“ Yokohama, 5-10 August 2007, Japan.
9. Jochen K. Lehmann, Sergey P. Verevkin, Svetlana A. Kozlova, Andreas Heintz, Kalorimetrische Untersuchungen des Mizellbildungsprozesses der ionischen Flüssigkeiten [C16MIM]Cl and [C16MIM]BF4 in Wasser und in Ethylammoniumnitrat (EAN). GVC-Fachausschuß“ Thermodynamik“ und VDI-GET „Thermodynamik-Kolloquium“ 8./10. Oktober 2007 in Rostock.
10. S.A. Kozlova, J.K.Lehmann, S.P. Verevkin, A. Heintz, Calorimetric Study of the Micellation Process of [C16MIM]Cl and [C16MIM]BF4 in Aqueous Solution and Ethylammoniumnitrate.“, 5th International Forum "Life Science Automation 2007 28.-31.10.2007 - Washington D.C., USA
11. S.A. Kozlova, S.V. Verevkin, A. “Eigenschaften von ionischen Flüssigkeiten als „green solvent.“, Vortrag vorgestellt auf 6th International Forum "Life Science Automation 2008" 12.-13.10.2008 - Rostock.
12. Verevkin, S. P; Emel’yanenko, VN; Heintz, A. Ionic Liquids. Combination of Combustion Calorimetry with the High-Level Quantum Chemical Calculations to Derive Vaporization Enthalpies 20th IUPAC Conference on Chemical Thermodynamics, 3rd – 8th August 2008, Warszawa.
13. Emel’yanenko, VN; Verevkin, SP; Heintz, A.; Jones, R.G.; Licence, P.
Pyrrolidinium Based Ionic Liquids. Enthalpy of Formation of 1-Butyl-1-Methyl-pyrrolidinium Dicyanoamide from Thermochemical Measurements and from Ab Initio Calculations. 20th IUPAC Conference on Chemical Thermodynamics, 3rd – 8th August 2008, Warszawa.
14. Sergey P. Verevkin, Vladimir N. Emel’yanenko, Andreas Heintz
Combination of combustion calorimetry with the high-level quantum chemical calculations to derive vaporisation enthalpies of ionic liquids. "Thermodynamik-Kolloquium" und "Ingenieurdaten", 24.-26. September 2008, Universität Erlangen, Germany
15. Sergey P. VerevkinApplied Thermodynamics and Thermochemistry of Ionic Liquids and their Mixtures with other Solvents.1st Sino-German Symposium on Ionic Liquids, November 2nd-5th 2008, Dalian, China.
16. Sergey P. VerevkinApplied Thermodynamics and Thermochemistry of Ionic Liquids and their Mixtures with other Solvents. 1st Asia Pacific Conference on Ionic Liquids and Green Processes, November 5th-9th 2008, Beijing, China.
17. Andreas Heintz, Vladimir N. Emel’yanenko, Sergey P. Verevkin, Thermochemistry of Ionic Liquids – a Balance between Experiments and ab initio Calculations. International Bunsen Discussion Meeting, Influence of Ionic Liquids on chemical and physicochemical reactions, November 23-25, 2008, Clausthal-Zellerfeld, Germany.
18. Vladimir N. Emel’yanenko, Sergey P. Verevkin, Andreas Heintz Thermochemistry of Ammonium Based Ionic Liquids. Enthalpies of Formation of tetra-Alkyl-Ammonium Nitrates from Combustion Calorimetry and from Ab Initio Calculations. 18. Ulmer Kalorimetrietage, 18-20.03.2009, Freiberg/Sa., Germany.
19. Sergey P. Verevkin, Vladimir N. Emel’yanenko, Andreas Heintz
Thermochemistry of Ionic Liquids – a Balance Between Calorimetric Experiments and First Principle Calculations 18. Ulmer Kalorimetrietage, 18-20.03.2009, Freiberg/Sa., Germany.
20. Verevkin, Sergey, Vladimir N. Emel’yanenko, Andreas Heintz
Thermochemistry of Ammonium Based Ionic Liquids. Enthalpies of Formation of tetra-Alkyl-Ammonium Nitrates from Combustion Calorimetry and from Ab Initio Calculations Coil-3 2009. 3rd Congress on Ionic Liquids May 31 - June 4 2009, Cairns Australia
21. Verevkin, Sergey, Vladimir N. Emel’yanenko, Andreas Heintz
Vaporization Enthalpies of Ionic Liquids – The Splits Between Calorimetric Experiments and First Principle Calculations Coil-3 2009. 3rd Congress on Ionic Liquids May 31 - June 4 2009, Cairns Australia
22. Verevkin, Sergey When the Things Are Not Rational As They Seem: Vaporization of an Ionic Liquid Upside Down Coil-3 2009. 3rd Congress on Ionic Liquids May 31 - June 4 2009, Cairns Australia
23. Verevkin, Sergey Vaporization Enthalpies of Ionic Liquids – The Alliance Among Experiments, First Principle, and Additive Calculations Pre-symposium Workshop on Recent Advances in Theoretical Approaches to Ionic Liquids, 31th May 2009, Cairns, Australia.
24. P. Eiden, U. Preiss, S. Verevkin, I. Krossing, Straightforward In Silico Prediction of the Melting Points of Ionic Liquids? Pre-symposium Workshop on Recent Advances in Theoretical Approaches to Ionic Liquids, 31th May 2009, Cairns, Australia
24. V.N. Emel’yanenko, S.P. Verevkin, A. Heintz VAPORIZATION ENTHALPIES OF IONIC LIQUIDS – THE SPLITS BETWEEN CALORIMETRIC EXPERIMENTS AND FIRST PRINCIPLE CALCULATIONS 17th International Conference on Chemical Thermodynamics in Russia, 29.06-03.07.2009, Kazan.
25. S.P. Verevkin, V.N. Emel’yanenko WHEN THE THINGS ARE NOT RATIONAL AS THEY SEEM: VAPORIZATION OF AN IONIC LIQUID UPSIDE DOWN 17th International Conference on Chemical Thermodynamics in Russia, 29.06-03.07.2009, Kazan.
26. Sergey P. Verevkin, Vladimir N. Emel’yanenko, Andreas Heintz, Thermochemistry of Ionic Liquids – Obey Thermodynamic Properties of Imidazolium Based Ionic Liquids Additive Group-Contribution Methods? "Thermodynamik-Kolloquium" und "Ingenieurdaten", 5.-7. Oktober 2009, Technische Universität Berlin, Germany
27. Sergey P. Verevkin ; Richardas Ralys, Vladimir N. Emel’yanenko
When the Things Are Not Rational As They Seem: Vaporization of an Ionic Liquid Upside Down EUCHEM, 14-19.03.2010, Bamberg, Germany
28. Dzmitry H. Zaitsau, Vladimir N. Emel’yanenko, Sergey P. Verevkin, Andreas Heintz Thermochemistry of Sulfur Containing Ionic Liquids – First Experiences with the Rotating Bomb Combustion Calorimetry. EUCHEM, 14-19.03.2010, Bamberg, Germany
29. Sergey. P. Verevkin, Richardas Ralys, Dymitry H. Zaitsau, Vladimir N. Emelyanenko, Christoph Schick, Natalia Pappe, Peter Wasserscheid Validation of the thermogravimetric method for measurements of vaporization enthalpies of very low volatile compounds. EUCHEM, 14-19.03.2010, Bamberg, Germany
30. Dzmitry H. Zaitsau, Richardas Ralys, Vladimir N. Emel’yanenko, Sergey P. Verevkin, Elena Reichert, Rolf Hempelmann Thermochemistry of Ammonium Based Ionic Liquids. Enthalpies of Formation of tri-Alkyl-Ammonium MethylSulfonates from Combustion Calorimetry, TGA, DSC, and from Ab Initio Calculations EUCHEM, 14-19.03.2010, Bamberg, Germany
Rolf Hempelmann, Universität des Saarlandes
Project: Dynamics of Ionic Liquids by means of Quasielastic Neutron Scattering
1. R. Hempelmann (Ed.), Progress in Physical chemistry Vol. 2, Materials Dominated by their Interphases, Oldenbourg, München 2008, ISBN 987-3-486-58629-9
2. H. Natter und R. Hempelmann, “Nanocrystalline Metals prepared by Electrodeposition”, Z. Phys. Chem. 222, 1-236 (2008)
3. R. Hempelmann, H. Natter, “Nanostructured Metals and Alloys Deposited from Ionic Liquids”, in Frank Endres, Douglas McFarlane und Andrew Abbott (Hrsg.), Electrodeposition in Ionic Liquids, Viley-VCH, Weinheim 2007
4. J.P. Embs, E. Reichert und R. Hempelmann, “Dynamics of Room Temperature Ionic Liquids by means of Quasielastic Neutron Scattering”, Swiss Neutron News 32, 4-11 (2007)
5. H. Natter, M. Bukowski, R. Hempelmann, S. Zein El Abedin, E. M. Moustafa und F. Endres, Electrochemical deposition of nanostructured metals and alloys from ionic liquids, Z. Phys. Chem. 220, 1275-1291 (2006)
6. S. Zein El Abedin, E. M. Moustafa, R. Hempelmann, H. Natter und F. Endres, Electrodeposition of nano- and microcrystalline aluminium in different air and water stable ionic liquids, ChemPhysChem. 7, 1535-1543 (2006)
7. S. Zain El Abedin, E. M. Mostafa, R. Hempelmann, H. Natter und F. Endres, Additive free electrodeposition of nanocrystalline aluminium in a water and air stable ionic liquid, Electrochemistry Communications 7, 1116-1121 (2005)
8. J.P. Embs, “Dynamics of RTILs by means of Quasielastic Neutron Scattering (QENS)”, invited talk(SPP - Meeting in Bamberg, December 2007)
9. J.P. Embs, “Dynamics
of RTILs by means of Quasielastic Neutron Scattering (QENS)”, invited
talk(SPP - Meeting in Bamberg, December 2007)
10. J.P. Embs, “QENS - Quasielastic Neutron Scattering - a method to probe dynamics in liquids on a molecular scale”, invited talk(SPP-WinterSchool in Leipzig, February 2008)
11. J.P. Embs, “Dynamics of ionic liquids (ILs) by means of Quasielastic Neutron Scattering (QENS)”, 13th International Seminar on Neutron Investigation in Condensed Matter, Plenary lecture, Poznan (Poland). May 2008
12. J.P. Embs, R. Hempelmann, “Dynamics of RTILs by means of Quasielastic Neutron Scattering (QENS)”, poster (SPP - Meeting in Bamberg, June 2007)
13. J.P. Embs, R. Hempelmann, “Dynamics of RTILs by means of Quasielastic Neutron Scattering (QENS)”, poster (SPP - Meeting in Bamberg, December 2007)
14. J.P. Embs, E. Reichert & R. Hempelmann,“Dynamics of ionic Liquids by means of QENS”, poster, Bunsentagung, May 2008 in Saarbrücken
Jürgen Janek, Justus-Liebig-Universität Gießen
Project: Interfaces between ionic liquids and low temperature plasmas - A novel type of fluid/fluid interface
1. Electrodeposition of Metals for Micro- and Nanostructuring at Interfaces between Solid, Liquid and Gaseous Conductors: Dentrites, Whiskers and Nanoparticles, K. Peppler, M. Pölleth, S. Meiss, M. Rohnke, J. Janek, Z. Phys. Chem. 220 (2006) 1507-1527
2. Plasma-Electrochemical Deposition of Nanoscale Metals and Semiconductors in Ionic Liquids, S. A. Meiss, M. Rohnke, L. Kienle, S. Z. El Abedin, F. Endres, and J. Janek, ChemPhysChem. 8 (2007) 50-53
3. Ionic liquids as green electrolytes for electrodeposition of nanomaterials, S. Zein El Abedin, M. Pölleth, S. A. Meiss, J. Janek, F. Endres, Green Chemistry 9(6) (2007) 549-553
4. Plasma electrochemistry with ionic liquids, M. Pölleth, M. Rohnke, S. A. Meiss, and Jürgen Janek, Book chapter, In: Electrochemistry of Ionic Liquids (Hrsg.: F. Endres, D. MacFarlane), to be published in 2008
5. Electrochemistry at the Ionic Liquid/Plasma Interface. Poster (Bamberg, June 2007)
Barbara Kirchner, Universität Leipzig
Project: Theoretical investigation of intermolecular forces in ionic liquids: Dynamics and structure of ionic liquids and interaction with other chemicals with respect to reaction and solvent properties
1. P. Nockemann, B. Thijs, S. Pittois, J. Thoen, C. Glorieux, C. J. K. Van Hecke, L. Van Meervelt, B. Kirchner and K. Binnemans, "A task-specific ionic liquid for solubilizing metal oxides", J. Phys. Chem. B, 110 (2006) 20978-20992
2. B. Kirchner and A. P. Seitsonen, "Green Chemistry from super computers: Car-Parrinello Simulations of Emim-Chloroaluminates Ionic Liquids", Chapter in "High Performance Computing in Science and Engineering"; Nagel, Kröner, Resch(Eds.) Springer, Berlin Heidelberg (2007) 157-172
3. B. Kirchner and A. P. Seitsonen, "Ionic liquids from Car-Parrinello simulations. II. Structural diffusion leading to diverse anions in chloraluminate ionic liquids", Inorg. Chem., 47 (2007) 2751-2754
4. P. Nockemann, B. Thijs, K. Driesen, C. J. K. Van Hecke, L. Van Meervelt, S. Kossmann, B. Kirchner and K. Binnemans, "Choline saccharinate and choline acesulfamate: ionic liquids with low toxicity", J. Phys. Chem. B, 111 (2007) 5254-5263
5. J. Thar, R. Hovorka and B. Kirchner, "Basis set superposition error along the free-energy surface of the water dimer", J. Chem. Theor. Comp., 3 (2007) 1510-1517
6. B. Kirchner, "Theory of complicated liquids". Phys. Rep., 1-3 (2007) 1-111
7. C. Spickermann, S. B. C. Lehmann and B. Kirchner, "Introducing phase transition to quantum chemistry – From Trouton’s rule to first principles vaporisation entropies", J. Chem. Phys. 128 (2008) 244506
8. J. Thar and B. Kirchner, "First-principles Molecular Dynamics Simulations of Liquids and Solvents," John von Neumann Institute for Computing, Jülich Symposium 20-21 Feb. 2008, NIC Series Proceedings, 39 (2008) 2049-2071
9. J. Thar, S. Zahn and B. Kirchner, "When Is a Molecule Properly Solvated by a Continuum Model or in a Cluster Ansatz? A First-Principles Simulation of Alanine Hydration", J. Phys. Chem. B, 112 (2008) 1456-1464
10. S. Zahn, F. Uhlig, J. Thar, C. Spickermann and B. Kirchner, "Intermolecular forces in an ionic liquid ([Mmim][Cl]) versus Those in a typical salt(NaCl)". Angew. Chem. Int. Ed. 47 (2008) 3639-3641
11. C. Spickermann, J. Thar, S. B. C. Lehmann, S. Zahn, J. Hunger, R. Buchner, P. A. Hunt, T. Welton and B. Kirchner, "Why are ionic liquid ions mainly associated in water? A Car–Parrinello study of 1-ethyl-3-methyl-imidazolium chloride water mixture", J. Chem. Phys., 129 (2008) 104505
12. S. Zahn, B. Kirchner, "Validation of dispersion corrected DFT-approaches for ionic liquid systems", J. Phys. Chem. A, 112 (2008) 8430-8435
13. S. Zahn, G. Bruns, J. Thar and B. Kirchner, "What keeps ionic liquids in flow? "Phys. Chem. Chem. Phys., 10 (2008) 6921-6924
14. S. B. C. Lehmann, C. Spickermann and B. Kirchner, "Quantum Cluster Equilibrium Theory Applied in Hydrogen Bond Number Studies of Water. 1. Assessment of the Quantum Cluster Equilibrium Model for Liquid Water" J. Chem. Theory Comput., 5 (2009) 1640–1649
15. S. B. C. Lehmann, C. Spickermann and B. Kirchner, "Quantum Cluster Equilibrium Theory Applied in Hydrogen Bond Number Studies of Water. 2. Icebergs in a Two-Dimensional Water Continuum?" J. Chem. Theory Comput., 5 (2009) 1650–1656
16. J. Thar and B. Kirchner, "Relativistic all-electron molecular dynamics simulations", J. Chem. Phys, 130 (2009) 124103
17. B. Kirchner, "Theoretical investigation of ionic liquids ", Top. Curr. Chem., 2009, DOI 10.1007/128.2009.36
18. W. Zhao, F. Leroy, B. Heggen, S. Zahn, B. Kirchner, S. Balasubramanian and F. Müller-Plathe, "Are There Stable Ion-Pairs in Room-Temperature Ionic Liquids? Molecular Dynamics Simulations of 1-n-Butyl-3-methylimidazolium Hexafluorophosphate", J. Am. Chem. Soc. (2009), 131, 15825.
19. J. Thar, M. Brehm, A. P. Seitsonen and B. Kirchner, "Unexpected Hydrogen Bond Dynamics in Imidazolium-Based Ionic Liquids", J. Phys. Chem. B (2009), 113, 15129.
20. P. Nockemann, M. Pellens, K. Van Hecke, L. Van Meervelt, J. Wouters, B. Thijs, E. Vanecht, T. N. Parac-Vogt, H. Mehdi, S. Schaltin, J. Fransaer, S. Zahn, B. Kirchner and K. Binnemans, "Tuning of the Coordinating Abilities of Nitrile Functionalized Ionic Liquids: Application to Electroactive Cobalt(II) Complexes", Chem. Eur. J. 16, (2010), 1848.
21. S. Zahn, J. Thar and B. Kirchner, "Structure and dynamics of the protic ionic liquid mono-methylammonium nitrate ([CH3NH3][NO3])", J. Chem. Phys. 132, (2010), 124506.
22. S. B. C. Lehmann, M. Roatsch, M. Schöppke and B. Kirchner, "On the physical origin of the cation-anion intermediate bond in ionic liquids. Part I: Placing a (weak) hydrogen bond between two charges", Phys. Chem. Chem. Phys., accepted.
23. S. Zahn and B. Kirchner, "Ionic Liquids", John von Neumann Institute for Computing, Jülich Symposium 24-25 Feb. 2010, NIC Series Proceedings, submitted
24. N. Van Hung, N. Bao Trung and B. Kirchner, "Anharmonic correlated Debye model Debye-Waller factors", Physica B, 405 (2010) 2519-2525
25. V. Kempter and B. Kirchner, "The role of hydrogen atoms in interactions involving imidazolium-based ionic liquids", J. Mol. Struct., 972 (2010) 22-34
Udo Kragl, Universität Rostock
Project: Understanding the interaction between enzymes, ionic liquids, dissolved substrates and water for reactions in solution and gas phase
1. Dreyer, S., Salim P., Kragl, U. Driving forces of protein partitioning in an ionic liquid-based aqueous two-phase system Biochemical Engineering Journal 46, 176-185 (2009)
2. Dreyer, S.; Kragl, U., "Ionic liquids for aqueous two phase extraction and stabilisation of enzymes". Biotechnology and Bioengineering, 99, (2008), 1416-1424
3. Ludwig, R.; Kragl, U., "Do We Understand the Volatility of Ionic Liquids?", Angewandte Chemie – International Edition, 46, 6582-6584 (2007)
4. Izak, P.; Köckerling, A.; Kragl, U., "Solute transport from aqueous mixture throught supported ionic liquid membrane by pervaporation", Desalination, 199, 96-98 (2006)
5. Izak, P.; Köckerling, M.; Kragl, U., "Stability and selectivity of multiphase membrane, consisting of dimethylpolysiloxane on an ionic liquid, used in the separation of solutes from aqueous mixture by pervaporation", Green Chemistry 8, 947-948 (2006)
6. Dreyer, S.; Lembrecht, J.; Schumacher, J., Kragl, U., "Enzyme catalysis in non-aqueous media – past-present-future in R. Patel (Ed.) Biocatalysis in the Pharmaceutical and Biotechnology Industries (2006), CRC-Press, Taylor & Francis Group, Boca Raton, pp 791-828
7. Dorbritz, S.; Ruth, W.; Kragl, U., "Investigation on aggregate formation of ionic liquids", Adv. Synth. Cat. 347, 1273-1279 (2005).
Friedrich Kremer, Universität Leipzig
Project: Physicochemical characterisation of ionic liquids-mediated peptide acylation reactions
1. Sangoro, J.R., Serghei, A., Naumov, S., Galvosas, P., Kärger, J., Wespe, C., Bordusa, F., and Kremer, F. (2008) Charge transport and mass transport in imidazolium-based ionic liquids. Phys. Rev. E 77, 051202, (2008).
2. Sangoro, J.R., Iacob, C., Serghei, A., Naumov, S., Galvosas, P., Kärger, J., Wespe, C., Bordusa, F., Stoppa, A., Hunger, J., Buchner, R., and Kremer, F., Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid. J. Chem. Phys. 128 214509, (2008).
3. Iacob, C., Sangoro, J. R., Serghei, A., Korth, Y., Naumov, S., Friedrich, C., Kärger, J. and Kremer, F. Charge transport and glassy dynamics in imidazole-based liquids. J. Chem. Phys. 129, 234511, (2008).
4. Sangoro, J. R., Iacob, C., Serghei, A., Friedrich, C., and Kremer, F., Universal scaling of charge transport in glass-forming ionic liquids. Phys. Chem. Chem. Phys. 11, 913, (2009).
5. Sangoro, J. R., Turky, G., Abdel-Rehim, M., Naumov, S., Ghoneim, A., Kärger, J., and Kremer, F., Charge transport and dipolar relaxations in hyperbranched polyamide amines. Macromolecules 42, 1648-1651, (2009).
6. Min, Y., Akbulut, M., Sangoro, J. R., Kremer, F., Prud’homme, R. K., Israelachvili, J., Measurement of forces across room temperature ionic liquids between mica surfaces. J. Phys. Chem. C 113, 16445 - 16449, (2009)
7. Krause, C., Sangoro, J.R., Iacob, C. and Kremer, F., Charge transport and dipolar relaxations in imidazolium-based ionic liquids. J. Phys. Chem. B, 114, 382-386, (2010).
8. Serghei, A., Tress, M., Sangoro, J. R., and Kremer, F. (2009) Electrode polarization and charge transport at metal-electrolyte interfaces. Phys. Rev. B, 80 184301.
9. Sangoro, J.R., Kärger, J., and Kremer, F., Broadband Dielectric Spectroscopy as a tool to study diffusion coefficients in conducting glass-forming systems. Dielectric Newsletter 24, 5, (2009).
10. Turky, G., Sangoro, J. R., Abdel-Rehim, M., and Kremer, F., Secondary relaxations and electrical conductivity in hyperbranched polyester amides. J. Polym. Sci. B: Polym. Phys., doi: 10.1002/polb.21966 (2010).
11. Iacob, C., Sangoro, J. R., Papadopoulos, P., Schubert, T., Naumov, S., Valluilin, R., Kärger, J. and Kremer, F. (2010). Charge transport and diffusion of ionic liquids in nanoporous silica membranes. Submitted to: Phys. Chem. Chem. Phys.
12. Sangoro, J.R., and Kremer, F. (2010). Dielectric properties of ionic liquids. Dielectric Briefs, submitted.
13. Zech, O. Hunger, J., Sangoro, J. R., Kremer, F. Kunz, W., and Buchner, R. (2010). Correlation between polarity parameters and dielectric properties of [Na][TOTO] – a sodium-based ionic liquid. Submitted to: Green Chemistry.
14. Kremer, F., Serghei, A., Sangoro, J. R., Tress, M., and Mapesa, E. U. (2010) Broadband dielectric spectroscopy in nano-(bio)-physics. IEEE Trans. CEIDP, in press.
Stefan Krischok, Technische Universitaet Ilmenau
Project: Electronic structure of ionic liquids surfaces - temperature dependence, solvation properties and radiation induced degradation
1. J. Guenster, O. Hoefft, S. Krischok, R. Souda, A time-of-flight secondary ion mass spectroscopy study of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide RT ionic liquid, Surface Science 602 (2008), 3403.
2. M. Brettholle, O. Hoefft, L. Klarhoefer, S. Mathes, W. Maus-Friedrichs, S. Zein El Abedin, S. Krischok, J. Janek, F. Endres, Plasma Electrochemistry in ionic liquids: deposition of copper nanoparticles, Physical Chemstry Chemical Physics, 12 (2010), 1724.
3. T. Ikari, A. Keppler, M. Reinmoeller, W.J.D. Beenken, S. Krischok, M. Marschewski, W. Maus-Friedrichs, O. Hoefft, F. Endres, Surface electronic structure of imidazolium-based ionic liquids studied by electron spectroscopy, e-Journal of Surface Science and Nanotechnology, 8 (2010) 241.
Ingo Krossing, Albert-Ludwigs-Universität Freiburg
Project: Why are ILs liquid?: Theoretical, empirical and experimental investigations of the fundamental properties of ionic liquids; including melting points, viscosities and dielectric constants. Low temperature crystallization and x-ray structure determination of RT-ILs
1. Ingo Krossing and John Slattery, "Semi-Empirical Methods to Predict the Physical Properties of Ionic Liquids: An Overview of Recent Developments", Z. Physik. Chem. 220, 1343-1360 (2006)
2. J. Slattery, C. Daguenet, P. Dyson, I. Krossing, H. Weingärtner, A.Oleinikova, Chihiro Wakai, "The dielectric response of room-temperature ionic liquids.”, J. Phys. Chem. A., 110, 12682-12688 (2006)
3. Ingo Krossing, John M. Slattery, Corinne Daguenet, Paul J. Dyson, A. Oleinikova, and H. Weingärtner, “Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies”, J. AM. CHEM. SOC., 128, 13427-13434 (2006)
4. H. Weingärtner, P. Sasisanker, C. Daguenet, P.J. Dyson, I. Krossing, J. M. Slattery, and T. Schubert, “The Dielectric Response of Room-Temperature Ionic Liquids: Effect of Cation Variation”, J. Phys. Chem. B, 111, 4775-4780 (2007)
5. J. M. Slattery, C. Daguenet, P. Dyson, T. J. S. Schubert, and I. Krossing, "Predicting the physical properties of ionic liquids: A volume-based approach", Angew. Chem. 119, 5480–5484 (2007)
6. P. Eiden, Q. L., S. Zein El Abedin, F.
Endres, I. Krossing, "An experimental and theoretical study of the aluminum species present in mixtures of AlCl_3 with the ionic liquids [BMP]Tf_2 N and [EMIm]Tf_2 N." , Chem. Eur. J. 15, 3426-3434 (2009).
7. U. Preiss, S. Bulut and I. Krossing*, "In Silico Prediction of the Melting Point of Ionic
Liquids: A Case Study", submitted to J. Chem. Phys. in May 2010.
8. U.P.R.M. Preiss, J. M. Slattery, I. Krossing, "In Silico Prediction of Molecular Volumes, Heat Capacities, and Temperature-Dependent Densities of Ionic Liquids.", Industrial & Engineering Chem. Res. 48, 2290-2296 (2009).
9. U. Preiss, V. N. Emel'yanenko, S. P. Verevkin, D. Himmel,
Y. U. Paulechka, I. Krossing, "The Temperature-Dependent Prediction of the Liquid Entropy of Ionic Liquids.", ChemPhysChem, in Revision in June 2010.
10. I. Raabe, K. Wagner, K. Guttsche, M. Wang, M. Grätzel, G.
Santiso-Quiñones, and I. Krossing, "Tetraalkylammonium Salts of Weakly Coordinating Aluminates: Ionic Liquids, Materials for Electrochemical Applications and Useful Compounds for Anion Investigation" Chem. Eur. J. 15, 1966-1976 (2009).
11. S. Bulut, P. Klose, M.-M. Huang, H. Weingärtner, P. J.
Dyson, G. Laurenczy, C. Friedrich, J. Menz, K. Kümmerer, and I.
Krossing*, "Synthesis of Room Temperature Ionic Liquids with the weakly coordinating [Al(OR^F )_4 ]^-- Anion (R^F = C(H)(CF_3 )_2 ) and the Determination of their Principal Physical Properties" , in press with Chem. Eur. J. in June 2010.
12. U. Preiss, C. Jungnickel, J. Thoeming, I. Krossing, J.
Luczak, M. Diedenhofen, A. Klamt, "Predicting the Critical Micelle Concentrations of Aqueous Solutions of Ionic Liquids and Other Ionic Surfactants." Chem. Eur. J., 15, 8880-8885, (2009).
13. M.-M. Huang, S. Bulut, I. Krossing,* H.
Weingärtner, "Are hydrodynamic models suited for describing the reorientational dynamics of ions in ionic liquids? A case study of methylimidazolium tetra(hexafluoroisopropoxy)aluminates." submitted to the Journal of Chemical Physics in March 2010.
14. Y. Yu, G. Dlubek, R. Krause-Rehberg, W. Beichel, S.
Bulut, N. Pogodina, I. Krossing, and Ch. Friedrich, "The free volume in an imidazolium triflylimide ionic liquid from positron lifetime: amorphous, crystalline and liquid states." , submitted to J. Chem. Phys. (AIP).
Martin Köckerling, Universität Rostock
Project: Ionic liquids with transition metal complex anions - magnetic ionic liquids
1. M. Geppert-Rybcynska*, J. K. Lehmann, T. Peppel, M. Köckerling, A. Heintz, „Studies of physicochemical and thermodynamic properties of the paramagnetic 1-alkyl-3-methylimidazolium ionic liquids (EMIm)2[Co(NCS)4] and (BMIm)2[Co(NCS)4]“, J. Chem. Eng. Data, 2010, submitted.
2. T. Peppel & M. Köckerling*, „Salts with the 1,3-Dibutyl-2,4,5-trimethyl-imidazolium cation: (DBTMIm)X (X = Br, PF6) and (DBTMIm)2[MBr4] (M = Co, Ni)”, Z. Anorg. Allg. Chem., 2010, submitted.
3. T. Peppel & M. Köckerling*, „Synthesis and Structure of 1-Ethyl-2,4,5-tri(phenyl)-1H-imidazole (Ethyl-Lophin)“, J. Struct. Chem., 2010, submitted.
4. T. Peppel, M. Köckerling*, M. Geppert-Rybczynska, R. V. Ralys, J. K. Lehmann, S. P. Verevkin & A. Heintz*, „Niedrigviskose paramagnetische Ionische Flüssigkeiten mit zweifach negativ geladenen [CoII(NCS)4]2–-Ionen“, Angew. Chem., 2010, angenommen.
5. A. Flemming, M. Hoffmann & M. Köckerling*. “Tetracyanidoborates with sterically demanding phosphonium cations – temperature stable Ionic Liquids”, Z. Anorg. Allg. Chem., 2010, 636, 562-568.
6. T. Peppel & M. Köckerling*, “X-ray structure of 3-(1H-imidazol-1-yl)propanenitrile”, Acta Cryst. E, 2009, E65, o2480.
7. T. Peppel & M. Köckerling*, “Crystal structure of 2,4,5-Tribromo-1-methyl-1H-Imidazole, C4H3N2Br3”, Z. Krist. NCS, 2009, 224, 597-598.
8. A. Bernsdorf, H. Brand, R. Hellmann, M. Köckerling, A. Schulz*, A. Villinger & K. Voss, „Synthesis, Structure, and Bonding of Weakly Coordinating Anions Based on CN-Adducts“, J. Am. Chem. Soc., 2009, 131, 8958-8970.
9. S. A Kozlova, S. P Verevkin, A. Heintz*, T. Peppel, & M. Köckerling, „Paramagentic Ionic Liquid 1-Butyl-3-methylimidazolium Tetrabromidocobaltate(II): Activity Coefficients at Infinite Dilution of Organic Solutes and Crystal Structure”, J. Chem. Eng. Data, 2009, 54, 1524-1528.
10. S. A Kozlova, S. P Verevkin*, A. Heintz, T. Peppel, & M. Köckerling, „Activity Coefficients at Infinite Dilution of Hydrocarbons, Alkylbenzenes, and Alcohols in the Paramagnetic Ionic Liquid 1-Butyl-3-Methyl-Imidazolium Tetrachloridoferrate(III) Using Gas-Liquid Chromatography”, J. Chem. Thermodynamics, 2009, 41, 330-333.
11. J. B. Willems, H. Rohm, C. Geers & M. Köckerling*, „Reversible ligand exchange in zirconium cluster compounds: Syntheses in ionic liquids and structures of [(Zr6Z)Br18]4- clusters (Z = Be, Fe)”, Inorg. Chem., 2007, 46, 6197-6203.
12. Magnetic Ionic Liquids: Properties and Structures. Poster(Bamberg, June 2007)
13 P. Izák, M. Köckerling & U. Kragl, Titel: Neue Mehrphasen-Membran zur Stofftrennung; supported ionic liquid membrane“, Patentnummer DE 102006024397B3, 2007.
Walter Leitner, Rheinisch-Westfälische Technische Hochschule Aachen
Project 1: Interactions, Dynamics and Structure in the Ionic Liquid-scCO2 system
Project 2: Chiral Functionalised Ionic Liquids as Reaction Media (with Dr. Jürgen Klankermayer)
1. M. Schmitkamp, D. Chen, W. Leitner, J. Klankermayer, G. Franciò, Chem. Commun. 2007, 4012-4014.
2. D. Chen, M. Schmitkamp, G. Franciò, J. Klankermayer, W. Leitner, Angew. Chem. 2008, 120, 7449-7451.
3. D. Chen, B. Sundararaju, R. Krause, J. Klankermayer, P. H. Dixneuf, W. Leitner, ChemCatChem 2010, 2, 55-57.
Thomas Lenzer and Kawon Oum, Georg-August-Universitaet Goettingen
Project: Time-resolved laser spectroscopy of rective and
nonreactive process in ionic liquids and their mixtures with carbon
dioxide
1. Lenzer, T, Lohse, P. W., Ehlers, F., Kopczynski, M. and Oum, K., "12'-Apo-beta-caroten-12'-al: A Unique 'Spy' Molecule for Probing Local Interactions in Ionic Liquids", Angew. Chem. Int. Ed., 49, 2230 (2010); Angew. Chem., 122, 2277 (2010).
2. Lohse, P. W., Ehlers, F., Oum K., Scholz, M. and Lenzer, T., "Ultrafast solvation dynamics of 12'-apo-?-carotenoic-12'-acid in [C6mim]+[Tf2N]-", Chem. Phys., doi: 10.1016/j.chemphys.2009.12.028
3. Lohse, P. W., Bürsing, R., Lenzer, T. and Oum, K., "Exploring 12'-Apo beta-carotenoic-12'-acid as an Ultrafast Polarity Probe for Ionic Liquids", J. Phys. Chem. B, 112, 3048 (2008).
Ralf Ludwig, Universität Rostock
1. K. Fumino, A. Wulf, S. Verevkin, A. Heintz, R. Ludwig, "Estimating enthalpies of vaporization of imidazolium-based ionic liquids from far infrared measurements.", ChemPhysChem, 11, 1623-1626, 2010. (Inside Cover)
2. R. Ludwig, A. Wulf, K. Fumino, P.F. Taday, "Combined THz, FIR and Raman spectroscopy studies of imidazolium based ionic liquids covering the frequency range between 2 and 300 cm-1", ChemPhysChem, 11: 349-353, 2010.
3. A. Wulf, K. Fumino, R. Ludwig, "Spectroscopic evidence for an enhanced anion-cation interaction due to hydrogen bonding in pure imidazolium ionic liquids", Angew. Chem., 49: 449-453, 2010. (Inside Cover)
4. K. Fumino, A. Wulf, R. Ludwig, comment on "New interpretation of the CH stretching vibrations in imidazolium-based ionic liquids", J. Phys. Chem. A, 114: 685-686, 2010.
5. R. Ludwig, "A simple geometrical explanation for the occurrence of specific large aggregated ions in some protic ionic liquids", J. Phys. Chem. B, 113: 15419-15422, 2009.
6.
Ralf Ludwig, Alexander Wulf, Koichi Fumino, Philip F Taday. “Combined
THz, FIR and Raman spectroscopy studies of imidazoliumbased ionic
liquids covering the frequency range between 2 and 300 cm-1”，ChemPhysChem, 11: 349-353,
2009.
7. D. Kerlé, R. Ludwig, A. Geiger, D. Paschek. “On the Temperature Dependence of the Solubility of Carbon Dioxide in Imidazolium-based Ionic Liquids.” J. Phys. Chem. B, 113: 12727-12735, 2009.
8. K. Fumino, A. Wulf, R. Ludwig. “The potential role of hydrogen bonding in aprotic and protic ionic liquids”. PCCP, 11: 8790-8794, 2009.
9. T. Köddermann, K. Fumino, R. Ludwig, J. N. C. Lopes, A. A. H. Pádua. “What far-infrared spectra can contribute to the development of force fields used in molecular dynamics simulations”. ChemPhysChem, 10: 1181-1186, 2009.
10. K. Fumino, A. Wulf, R. Ludwig. “Hydrogen Bonding in protic ionic liquids and reminiscence of water”, Angewandte Chemie, in print, 48: 3184-3186, 2009. (Hot Paper)
11. J. Kuss, J. Holzmann, R. Ludwig. “An Elemental Mercury Diffusion Coefficient for Natural Waters Determined by Molecular Dynamics Simulation”. Env. Sci. Tech., 100: 115901, 2009.
12. I. A. Shuklov, N. V. Dubrovina, E. Barsch, R. Ludwig, D. Michalik, A. Börner. “Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study”. Chem. Comm, 12, 1535-1537, 2009.
13. R. Ludwig, D. Paschek. “Applying the inductive effect for synthesizing low melting and low viscous imidazolium-based ionic liquids. ChemPhysChem, 10: 516-519, 2009.
14. R. Winter, R. Ludwig. “Editorial: The Complex Nature of Water at Molecular Interfaces”. ChemPhysChem, 9, 2635-2636, 2008.
15. J. Holzmann, R. Ludwig, A. Geiger, D. Paschek. “Temperature and concentration effects on the solvophobic solvation of methane in aqueous salt solutions”. ChemPhysChem, 9, 2722-2730, 2008.
16. J. Riemenschneider, J. Holzmann, R. Ludwig. “Salt effects on the structure of water probed by attenuated total reflection infrared spectroscopy and molecular dynamics simulations. ChemPhysChem, 9, 2731-2736, 2008.
17. K. Fumino, A. Wulf, R. Ludwig. “Strong, localized and directional H-bonds fluidize Ionic Liquids”. Angewandte Chemie, 47, 8731-8734, 2008. (Hot Paper)
18. T. Köddermann, R. Ludwig, D. Paschek.“ On the Validity of Stokes-Einstein and Stokes-Einstein-Debye Relations in Ionic Liquids and Ionic Liquids Mixtures”. ChemPhysChem, 9, 1851-1858, 2008
19. R. Ludwig. “Thermodynamical properties of ionic lqiuids - A cluster approach” Phys. Chem. Chem. Phys., 10: 4333-4339, 2008.
20. K. Fumino, A. Wulf, R. Ludwig, “The cation-anion interaction in Ionic-Liquids probed by far-infrared spectroscopy”. Angew. Chem., 120: 3890-3894, 2008. Angew. Chem. Int. Ed. Engl., 47: 3830-3834, 2008.
21. D. Paschek, T. Köddermann, R. Ludwig. “The Solvophobic Solvation and Interaction of Small Apolar Particles in Imidazolium-Based Ionic Liquids”. Phys. Rev. Lett., 100: 115901 2008.
22. T. Köddermann, D.Paschek, R. Ludwig. “Ionic Liquids: Dissecting the Heat of Vaporization. ChemPhysChem, 9: 549-555, 2008.
23. T. Köddermann, D.Paschek, R. Ludwig. “Molecular dynamics simulations of ionic liquids: A reliable description of structure, thermodynamics and dynamics”. ChemPhysChem, 8: 2464-2470, 2007.
24. J. Holzmann, R. Ludwig, D. Paschek, A. Geiger. “Pressure and salt effects: Two sides of the same coin?” Angew. Chem., 119: 9065-9069, 2007. Angew. Chem. Int. Ed. Engl., 46: 8907-8911, 2007. (Hot paper)
25. A. Wulf, K. Fumino, D. Michalik, R. Ludwig. “IR and NMR properties of Ionic Liquids: Do they tell us the same thing?” ChemPhysChem, 8: 2265-2269, 2007.
26. R. Ludwig, U. Kragl. “Do we understand the volatility of Ionic Liquids?”, Angew. Chem., 119: 6702-6704, 2007. Angew. Chem. Int. Ed. Engl., 46: 6582-6584, 2007.
27. A.Wulf, R. Ludwig, P.Sasisanker, H.Weingärtner, “Molecular Reorientation in Ionic Liquids. A Comparative Dielectric and Magnetic Relaxation Study”. Chem. Phys. Lett., 439: 323-326, 2007.
Gerd Maurer, Technische Universität Kaiserslautern
Project: Multiphase equilibria in systems containing ionic liquids: Experimental investigations of phenomena and molecular modeling
1. Á. Pérez-Salado Kamps, D. Tuma, J. Xia, G. Maurer, "Solubility of CO2 in the Ionic Liquid [bmim][PF6]", J. Chem. Eng. Data 2003, 48, 746-749
2. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of CO in the ionic liquid [bmim][PF6]", Fluid Phase Equilibria, 2005, 228-229, 207-211.
3. J. Kumelan, Á. Pérez-Salado Kamps, I. Urukova, D. Tuma, G. Maurer, "Solubility of oxygen in the ionic liquid [bmim][PF6]: Experimental and molecular simulation results", J. Chem. Thermodynamics 2005, 37, 595-602.
4. I. Urukova, J. Vorholz, G. Maurer, "Solubility of CO2, CO and H2 in the ionic liquid [bmim][PF6] from Monte Carlo Simulations", J. Phys. Chem. B, 109, 2005, 12154-12159.; Correction: ibid B 2006, 110, 18072.
5. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Mauer, "Solubility of H2 in the Ionic Liquid [bmim][PF6]", J. Chem. Eng. Data, 2006, 51, 11-14.
6. K. Sahandzhieva, D. Tuma, S. Breyer, Á. Pérez-Salado Kamp, G. Mauer, "Liquid-liquid equilibrium in mixtures of the ionic liquid 1-n-butyl3-methylimidazolium hexafluorophosphate and an alkanol", J. Chem. Eng. Data, 2006, 51, 1516-1525.
7. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Mauer, "Solubility of CO2 in the ionic liquid [hmim][Tf2N]", J. Chem. Termodynamics, 2006, 38, 1396-1401.
8. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Mauer, "Solubility of H2 in the ionic liquid [hmim][Tf2N]", J. Chem. Eng. Data, 2006, 51, 1364-1367.
9. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of CO2 in the Ionic Liquids [bmim][CH3SO4] and [bmim][PF6]", J. Chem. Eng. Data, 2006, 51, 1802-1807.
10. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of the single gases H2 and CO in the ionic liquid [bmim][CH3SO4]", Fluid Phase Equilibria, 2007, 260, 3-8.
11. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of the single gases methane and xenon in the ionic liquid [hmim][Tf2N]", Ind. Eng. Chem. Res. 2007, 46, 8236-8240.
12. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, |Solubility of the single gases methane and xenon in the ionic liquid [bmim][CH3SO4]“, J. Chem. Eng. Data 2007, 52, 2319-2324.
13. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, A.Yokozeki, M. B. Shiflett, G. Maurer, "Solubility of tetrafluoromethane in the ionic liquid [hmim][Tf2N]", J. Phys. Chem. B 2008, 112, 3040-3047.
14. Y. G. Dobryakov. D. Tuma, G. Maurer, "Activity coefficients at infinite dilution of alkanols in the ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium methyl sulphate and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) amide using the dilutor technique", J. Chem. Eng. Data 2008, 53, 2154-2162.
15. J. Kumelan, D. Tuma, G. Maurer, "Partial molar volumes of selected gases in some ionic liquids" Fluid Phase Equilibria 2009, 275, 132-144.
16. J. Kumelan, D. Tuma, S. P. Verevkin, G. Maurer, "The Solubility of hydrogen in the cyclic alkylene ester 1,2-butylene carbonate", J. Chem. Eng. Data 2008, 53, 2844-2850.
17. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of the single gases carbon monoxide and oxygen in the ionic liquid [hmim][Tf2N]", J. Chem. Eng. Data. 2009, 54, 966-971.
18. J. Kumelan, Á. Pérez-Salado Kamps, D. Tuma, G. Maurer, "Solubility of the single gases carbon dioxide and hydrogen in the ionic liquid [bmpy][Tf2N]", J. Chem. Eng. Data. 2009, accepted.
19. G. Maurer, Á. Pérez-Salado Kamps, "Solubility of Gases in Ionic Liquids, Aqueous Solutions and Mixed Solvents" in T.M. Letcher (Ed.) Developments and Applications in Solubility, RSC Publishing Cambridge, 2007, pp. 41-58
Harald Morgner, Universität Leipzig
Project: Investigations of ionic liquid – solute systems by surface sensitive spectroscopic techniques – part of the initiative “Shaping micro- and macroscopic properties of ionic liquid-solute systems”
1. Surface Properties of Ionic Liquids studied with NICISS. Invited talk(Bamberg, June 2007)
Anja-Verena Mudring, Ruhr-Universität Bochum
Project 1: Ionic Liquid Crystals
1. A.-V. Mudring, A. Babai, S. Arenz, R. Giernoth, K. Binnemans, K. Driesen, P. Nockemann: Strong Luminescence of rare earth compounds in ionic liquids: Luminescent properties of lanthanide(III) iodides in the ionic liquid 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide J. Alloys and Compounds, 2006, 418, 204.
2. A. Getsis, A.-V. Mudring: Ionic Liquid Crystals, Z. Anorg. Allg. Chem. 2006, 632, 2106.
3. A.-V. Mudring:Ionic Liquids – New Versatile Materials in: M. Lein (ed.) Proceedings of the NZIC 2006, Massey University Press, Palmerston North, Vol. 1, 91. ISBN-10: 0-473-11854-8
4. A. Getsis, A.-V. Mudring: [C12mim]4[EuBr6]Br×CH3CN: A Lanthanide Based Ionic Liquid Crystal, Z. Krist. Suppl. Vol. 2007, 041-01-id177.
5.
A. Getsis, A.-V. Mudring: Imidazolium Based Ionic Liquid Crystals:Structure, Photophysical and Thermal Behaviour of [Cnmim]Br•xH2O
(n = 12, 14; x=0, 1), Cryst. Res. Technol. 2008, 43, 1187.
6.
A. Getsis, A.-V. Mudring: Structural and Thermal Behaviour of the
Pyrrolidinium Based Ionic Liquid Crystals [C10mpyr]Br and [C12mpyr]Br,
Z. Anorg. Allg. Chem. 2009, 635, 2214.
7. A. Getsis, B. Balke, C. Felser, A.-V. Mudring: Luminescent, magnetic and liquid crystalline behavior of [C12mim]3[DyBr6] and structural characterisation of [C12mim]3[DyBr6]•2CH3CN, Crystal Growth and Design 2009, 9, 4429.
8. X. Wang, F. W. Heinemann, M. Yang, B. Melcher, M. Fekete, A.-V. Mudring, P. Wasserscheid, K. Meyer: Double alkyl-substituted, liquid crystalline imidazolium ionic liquids – new structural features, viscosity effects and thermal properties, Chem. Commun. 2009, 7405.
9. A. Getsis, A.-V. Mudring: A Luminescent Ionic Liquid Crystal: [C_12 mim]_4 [EuBr_6 ]Br, Eur. J. Chem. 2010, 2172.
10. A.-V. Mudring: Crystallization of Ionic Liquids: Theory and Techniques, Aust. J. Chem. 2010, 63, 544 (Review article).
11. A. Getsis, A-V. Mudring: Lanthanide containing ionic liquid crystals: EuBr_2 , SmBr_3 , TbBr_3 and DyBr_3 in C_12 mimBr, Z. Allg. Anorg. Chem. 2010, in press.
12. A. Getsis, A.-V. Mudring: Green and White Luminescence in Terbium-based Ionic Liquid Crystals, submitted.
Project 2: Transition Metals as Probes for IL Acidity
1. A.-V. Mudring: “Ionic Liquids and Optical Spectroscopy” in B. Kirchner: “Ionic Liquids” Topics Curr. Chem. 2010, 290, 285.
2. A.-V. Mudring: “Complexation studies of f-elements in ionic liquids” in: Solvent Extraction: Fundamentals to Industrial Applications, 2008, 2, 1271.
3. S. Pitula, A.-V. Mudring: “Synthesis, Structure, and Physico-optical Properties of Manganate(II)-Based Ionic Liquids” Chem. Eur. J. 2010, 16, 3355.
4. J. Bartosik, A.-V. Mudring: “[Ni(tmen)(acac)][B(Ph)_4 ] a probe for the anion basicity of ionic liquids”, Phys. Chem. Chem. Phys. 2010, 12, 4005.
5. S. Pitula, A.-V. Mudring, “Optical basicity of ionic liquids”, Phys. Chem. Chem. Phys. 2010, ASAP available.
6. A. Babai, S. Pitula, A.-V. Mudring, “Structural and electrochemical properties of Yb(III) in various ionic liquids”, Eur. J. Inorg. Chem. 2010, accepted.
Florian Müller-Plathe, Technische Universität Darmstadt
Project: Viscosities and other dynamic properties of ionic liquids by molecular dynamics simulations and structure-property relations
1. W. Zhao, H. Eslami, W. L. Cavalcanti, F. Müller-Plathe, A Refined All-Atom Model for the Ionic Liquid 1-n-Butyl 3-Methylimidazolium bis(Trifluoromethylsulfonyl)imide [bmim][Tf2N], Z. Phys. Chem. 221, 1647-1662, (2007)
2. W. Zhao, F. Leroy, S. Balasubramanian, and F. Müller-Plathe, The shear viscosity of the ionic liquid 1-n-butyl-3-methylimidazoliuim hexafluorophosphate [bmim][PF6] computed by reverse non-equilibrium molecular dynamics, J. Phys. Chem. B 2008, 112, 8129
3. W. Zhao, F. Leroy, B. Heggen, S. Zahn, B. Kirchner, S. Balasubramanian and F. Müller-Plathe, "Are There Stable Ion-Pairs in Room-Temperature Ionic Liquids? Molecular Dynamics Simulations of 1-n-Butyl-3-methylimidazolium Hexafluorophosphate", J. Am. Chem. Soc. 2009, 131, 15825
4. H. Ali Karimi-Varzaneh, F. Müller-Plathe, S. Balasubramanian and Paola Carbone, "Studying long-time dynamics of imidazolium-based ionic liquids with a systematically coarse-grained model", PCCP 2010, 12, 4714.
5. B. Heggen, W. Zhao, F. Leroy, A. J. Dammers, F. Müller-Plathe," Interfacial Properties of an Ionic Liquid by Molecular Dynamics", J. Phys. Chem B 2010, 114, 6954.
6. S.S. Sarangi, W. Zhao, F. Müller-Plathe, and S. Balasubramanian, "Stress relaxation and shear viscosity of liquid 1-butyl,3-methylimidazolium hexafluorophosphate", submitted
7. V. C. Weiss, B. Heggen, and F. Müller-Plathe, "Critical parameters and surface tension of the room temperature ionic liquid [bmim][PF6]: a corresponding-states analysis of experimental and new simulation data", J. Phys. Chem B, 2010, 114, 3599.
8. W. Zhao, F. Müller-Plathe, "Force field development and viscosity studies of ionic liquids using molecular dynamics simulations", poster(EUROMAT, Nürnberg, September 2007)
9. W. Zhao, F. Müller-Plathe, "Force field development and viscosity studies of ionic liquids using molecular dynamics simulations", invited talk (Bamberg, June, 2007)
10. W. Zhao, F. Müller-Plathe, "Viscosity and dynamics studies of ionic liquids using molecular dynamics simulations", invited talk (Bamberg, December, 2007)
11. W. Zhao, H. Karimi, F. Müller-Plathe, "Shear viscosity and dynamics studies of ionic liquids using molecular dynamics simulations", invited talk (Leipzig, spp-winterschool, February, 2008)
12. W. Zhao, F. Müller-Plathe, "Force field development and viscosity studies of ionic liquids using molecular dynamics simulations", poster (Bamberg, June, 2007)
13. W. Zhao, H. Karimi, F. Müller-Plathe, "Shear viscosity and dynamics studies of ionic liquids using molecular dynamics simulations", poster (Bamberg, December, 2007)
Bernd Rathke and Wolffram Schröer, Universität Bremen
Project: Characterization and Kinetics of Microheterogeneities in Ionic Liquids
1. V. R. Vale, B. Rathke, S. Will, W. Schröer, Liquid-Liquid Phase Behavior of Solutions of 1-Octyl- and 1-Decyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide (C8,10mimNTf2) in n-Alkyl Alcohols, Journal of Chemical Engineering Data. 55, 2030-2038 (2010)
Stefan Spange, Technische Universität Chemnitz
Project: Polarity of pure ionic liquids and at the phase boundary with inorganic solid catalysts
1. A. Oehlke, K. Hofmann, S. Spange, „New aspects on polarity of ionic liquids as
measured by solvatochromic probes“, New J. Chem. 2006, 30, 533-536.
2. R. Lungwitz, S. Spange, “Polarity of pure ionic liquids and at the phase boundary with inorganic solid catalysts”. Poster (JCF, Frühjahrsymposium, Chemnitz, March 2007)
3. R. Lungwitz, S. Spange, “Polarity of pure ionic liquids and at the phase boundary with inorganic solid catalysts”. Poster (EUROMAT, Nürnberg, September 2007)
4. R. Lungwitz, S. Spange, „A hydrogen bond accepting (HBA) scale for anions, including room temperature ionic liquids“, New J. Chem. 2008, 32, 392. “Hot article”
5. R. Lungwitz, M. Friedrich, W. Linert, S. Spange, „New aspects on the hydrogen bond donor (HBD) strength of 1-butyl-3-methylimidazolium room temperature ionic liquids“, New J. Chem. 2008, 32, 1493. “Inside front cover”
6. I. Bolz, S. Spange, “An Enolisable Barbiturate with Adjustable Hydrogen-Bonding Structure for UV/Vis Detection of Nucleic Acid Bases and Related Compounds”, Chem. Eur. J. 2008, 14, 9338.
7. K. Hofmann, K. Schreiter, A. Seifert, T. Rüffer, H. Lang, S. Spange, “Solvatochromism and linear solvation energy relationship of diol- and proline-functionalized azo dyes using the Kamlet-Taft and Catalan solvent parameter sets” New J. Chem. 2008, 32, 2180.
8. K. Schreiter, S. Spange, “Amino-acid-functionalized solvatochromic probes” J. Phys. Org. Chem. 2008, 21, 242.
9. R. Lungwitz, S. Spange, “Polarity of pure ionic liquids and at the phase boundary with inorganic solid catalysts”. Poster (JCF, Frühjahrsymposium, Rostock, March 2008)
10. R. Lungwitz, S. Spange, “Physi- and Chemisorption of Ionic Liquids onto Silica” Poster (ISOS XV, Jeju-Do, South Korea, June 2008.
11. R. Lungwitz, S. Spange, "Structure and Polarity of the Phase Boundary of N-Methylimidazolium Chloride/Silica" J. Phys. Chem. C, 2008, 112(49), 19443.
12. S. Spange, R. Lungwitz, “Solvatochromism as a tool to determine reliable polarity parameters of ionic liquids and solution of salts” Talk (EUCHEM, Kopenhagen, August 2008)
13. R. Lungwitz, S. Spange, “Polarity of pure ionic liquids and at the phase boundary with inorganic solid catalysts” Poster (EUCHEM, Kopenhagen, August 2008)
14. R. Lungwitz, V. Strehmel, S. Spange, “The dipolarity/polarisability of 1-alkyl-3-methyl-imidazolium ionic liquids as function of anion structure and the alkyl chain length” New J. Chem. 2010, 34, 1135.
15. I. Bolz, M. Bauer, A. Rollberg, S. Spange, “Chromophoric Barbituric Acid Derivatives with Adjustable Hydrogen-Bonding Patterns as Component for Supramolecular Structures” Macromol. Symp. 2010, 287, 8.
16. R. Lungwitz, S. Spange, "The polarity of Ionic Liquids measured by means of solvatochromic dyes” Poster (EUCHEM, Bamberg, March 2010)
17. R. Lungwitz, S. Spange, Th. Linder, J. Sundermeyer, " Physi- and Chemisorption of Ionic Liquids onto Silica” Poster (EUCHEM, Bamberg, March 2010)
18. V. Strehmel, R. Lungwitz, H. Rexhausen, S. Spange, “Relationship between Hyperfine Coupling Constants of Spin Probes and Empirical Polarity Parameters of Ionic Liquids” New J. Chem. 2010, DOI:10.1039/C0NJ00253D.
19. R. Lungwitz, Th. Linder, J. Sundermeyer, I. Tkatchenko, S. Spange, ”Synthesis of chemisorbed imidazolium and phosphonium cations by reaction of ionic liquid precursors with silica” Chem. Commun. 2010, accepted.
Annegret Stark, Friedrich-Schiller-Universität Jena
Project: Shaping micro- and macroscopic properties of ionic liquid-solute systems: multifunctional task-specific (solvent, catalyst, water scavenger) agents
1. A. Stark and K.R. Seddon, “Ionic Liquids“, in Kirk-Othmer Encyclopaedia of Chemical Technology, 5th Edit., Ed. A. Seidel, Vol. 26 (John Wiley & Sons, Inc., Hoboken, New Jersey, 2007), 836-920.
2. A. Stark, O. Braun, B. Ondruschka, “UV-Spectroscopic quantitative determination of non-aromatic amines in ionic liquids“, Anal. Sciences, 2008, 24, 681-683.
3. G. J. Mohr, H. Müller, B. Bussemer, A. Stark, T. Carofiglio, S. Trupp, R. Heuermann, Th. Henkel, D. Escudero and L. González, “Design of acidochromic dyes for facile preparation of pH sensor layers”, Anal. Bioanal. Chem., 2008, 392, 1411-1418.
4. A. Stark, P. Behrend, O. Braun, A. Müller, J. Ranke, B. Ondruschka and B. Jastorff “Purity specification methods for ionic liquids”, Green Chem., 2008, 10, 1152-1161.
5. A. Miloslavina, E. Leipold, M. Kijas, A. Stark, S. H. Heinemann and D. Imhof, “A room temperature ionic liquid as convenient solvent for the oxidative folding of conopeptides”, J. Pept. Sci., 2009, 15, 72-77.
6. A. Stark, “Ionic liquid structure-induced effects on organic reactions”, Top. Curr. Chem., Vol.: Ionic Liquids, B. Kirchner (ed.), 2009, accepted for publication, DOI: 10.1007/128_2009_43.
7. D. Reinhardt, D. Kralisch, G. Kreisel, B. Ondruschka and A. Stark, “Ionic Liquids and Green Chemistry: A Lab Experiment”, J. Chem Edu., 2010, 97, 196-201.
8. T. Gutmann, M. Sellin, H. Breitzke, A. Stark and G. Buntkowsky, “para-Hydrogen induced polarization in homogeneous phase – an example of how Ionic liquids affect homogenization and thus activation of catalysts”, Phys. Chem. Chem. Phys., 2009, submitted.
9. J. Zimmermann, B. Ondruschka and A. Stark, “Efficient synthesis of 1,3-dialkylimidazolium-based ionic liquids: The modified continuous Radziszewskireaction in a microreactor set-up", Org. Proc. Res. Dev., accepted.
10. F. Benaskar, V. Hessel, U. Krtschil, P. Löb, A. Stark, „Intensification
of the capillary-based Kolbe-Schmitt synthesis from resorcinol by reactive
ionic liquids, microwave heating or a combination thereof“, Org. Proc. Res.
Dev., 2009, 13, 970–982.
11. U.
Krtschil, V. Hessel, D. Reinhard, A. Stark, “Flow chemistry of the
Kolbe-Schmitt synthesis from resorcinol – process intensification by
alternative solvents, new reagents and advanced reactor engineering”, Chem.
Eng. Technol., 2009, 32, 1774-1789.
12. S.
P. Verevkin, V. N. Emel’yanenko, E. N. Stepurko, R. V. Ralys, D. H. Zaitsau, A.
Stark, “Biomass-derived platform chemicals: thermodynamic studies on the
conversion of 5-hydroxymethylfurfural into bulk intermediates”, Ind. Eng. Chem.
Res., 2009, 48, 10087-10093
13. A. Stark, B. Ondruschka, “Ionic liquids in the
manufacture of 5‑Hydroxymethylfurfural from saccharides. An example for the
conversion of renewable resources to platform chemicals”, in: Handbook of Green Chemistry: Green Solvents, Vol. 6 - Ionic Liquids, P. Wasserscheid, A. Stark (eds.), Wiley-VCH, 2010, 85-113.
14. D. Ott, D.
Kralisch, A. Stark, “Perspectives of ionic liquids as environmentally benign
substitutes to molecular solvents”, in: Handbook of Green Chemistry: Green
Solvents: 2, P. Wasserscheid, A. Stark
(eds.), Wiley-VCH, 2010, 309-334.
15. A. Stark, S. Huebschmann, M. Sellin, D. Kralisch, R. Trotzki, B. Ondruschka, "Microwave assisted Kolbe-Schmitt synthesis using ionic liquids or Dimcarb as reactive solvents", Chem. Eng. Technol., 2009, 32, 1730-1738.
16. A. Stark, M. Ajam, M. Green, H. G. Raubenheimer, A. Ranwell, B. Ondruschka, "Methathesis of 1-octene in ionic liquids and other solvents: effects of substrate solubility, solvent polarity and impurities" Adv. Synth. Catal., 2006, 348, 1934-1941.
17. M. Sellin, B. Ondruschka and A. Stark, "Hydrogen bonds acceptor properties of ionic liquids and their effect on cellulose solubility", T. Liebert, T. H. Heinze, K. Edgar (eds.), Vol. 1033, ACS Symp. Series, Washington DC, 2010, pp 121-135.
18. T. Bilezki, A. Stark, W. Imhof, "Ionic liquids as solvents for a ruthenium catalyzed C-H activation reaction: synthesis of heterocyclic compounds from α,β-unsaturated imines, carbon monoxide and ethylene", Monatsh. Chem., 2010, 141, 413–418.
19. C. Mrestani-Klaus, A. Richardt, Ch. Wespe, A. Stark, E. Humpfer, F. Bordusa,
"Basic applicability of HR-MAS NMR spectroscopy for structural studies of ionic
liquid/peptide systems", submitted to J. Phys. Chem.
20. A. Stark, J. Lifka, B. Ondruschka, "Verfahren zur kontinuierlichen Herstellung
von 5-Hydroxymethylfurfural mit Hilfe ionischer Flüssigkeiten", DE 102008009933,
2008.
21. G. Mohr, A. Stark, "Optische Sensoren zur Detektion von Ionen, Gasen und
Biomolekülen sowie Verfahren zu deren Herstellung und Verwendung", DE 102007053664, 2007.
22. Editor of Handbook of Green Chemistry: Green Solvents: 2, P. Wasserscheid, A. Stark (eds.), Wiley-VCH, 2010.
Hans-Peter Steinrück, Friedrich-Alexander-Universität Erlangen-Nürnberg
Project: Ionic liquid surface science
1. F. Maier, J. M. Gottfried, J. Rossa, D. Gerhard, P. S. Schulz, W. Schwieger, P. Wasserscheid, H.-P. Steinrück, "Surface Enrichment and Depletion Effects of Ions Dissolved in Ionic Liquids: An X-ray Photoelectron Spectroscopy Study“, Angew. Chem. 2006, 118, 7942-7944; Angew. Chem., Int. Ed. 2006, 45(46), 7778-7780.
2. J. M. Gottfried, F. Maier, J. Rossa, D. Gerhard, P. S. Schulz, P. Wasserscheid, H.-P. Steinrück, "Surface Studies on the Ionic Liquid 1-Ethyl-3-methylimidazo-lium Ethylsulfate Using X-Ray Phtoelectron Spectroscopy (XPS)”, Z. Phys. Chem. 2006, 220, 1439-1453.
3. N. Paape, W. Wei, A. Bösmann, C. Kolbeck, F. Maier, H.-P. Steinrück, P. Wasserscheid, and P.S. Schulz, "Chloroalkylsulfonate ionic liquids by ring opening of sultones with organic chloride salts", Chem. Comm. 2008, 33, 3867.
4. C. Kolbeck, M. Killian, F. Maier, N. Paape, P. Wasserscheid, and H.-P. Steinrück, "Surface characterization of functionalized imidazolium-based ionic liquids", Langmuir 2008, 24, 9500.
5. T. Cremer, M. Killian, J.M. Gottfried, N. Paape, P. Wasserscheid, F. Maier, H.-P. Steinrück, "Physical vapor deposition of [EMIM][Tf2N]: A new approach to the modification of surface properties with ultrathin ionic liquid films", ChemPhysChem 2008, 9, 2185.
6. K. Lovelock, C. Kolbeck, T. Cremer, N. Paape, P. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, "The influence of different substituents on the surface composition of ionic liquids studied using ARXPS, J. Phys. Chem. B, 2009, 113, 2854.
7. C. Kolbeck, K. R. J. Lovelock, T. Cremer, N. Paape, P. Wasserscheid, F. Maier, H.-P. Steinrück, “Influence of Different Anions on the Surface Composition of Ionic Liquids Studied Using ARXPS”, J. Phys. Chem. B 113 (2009) 8682-8688.
8. F. Maier, T. Cremer, C. Kolbeck, K.R.J. Lovelock, N. Paape, P.S. Schulz, P. Wasserscheid, H.-P. Steinrück, ”Insights into surface composition and enrichment effects of ionic liquids and ionic liquid mixtures”, Phys. Chem. Chem. Phys. 12 (2010) 1905-1915, invited contribution.
9. H.-P. Steinrück, “Surface Science goes liquid!”, Surf. Sci. 604 (2010) 481-485 (Invited Prospective Article).
10. M. Sobota, I. Nikiforidis, W. Hieringer, N. Paape, M. Happel, H.-P. Steinrück, A. Görling, P. Wasserscheid, M. Laurin, J. Libuda, “Towards Ionic Liquid Based Model Catalysis: Growth, Orientation, Conformation and Interaction Mechanism of [BMIM][Tf2N] Thin Films on an Ordered Alumina Surface”, Langmuir 26 (2010) 7199-7207.
11. T. Cremer, C. Kolbeck, K. R. J. Lovelock, N. Paape, P. S. Schulz, P. Wasserscheid, H. Weber, J. Thar, B. Kirchner, R. Wölfel, F. Maier and H.-P.-Steinrück, ”Towards a Molecular Understanding of Cation-Anion Interactions - Probing the Electronic Structure of Imidazolium Ionic Liquids by XPS, NMR and Theory”, Chemistry – A European Journal (accepted)
12. K. R. J. Lovelock, I. J. Villar-Garcia, F. Maier, H.-P. Steinrück, P. Licence, “Photoelectron Spectroscopy of Ionic Liquid Based Interfaces”, Chemical Reviews (in press)
Veronika Strehmel, Universität Potsdam
Project: Interactions between Ionic Liquids and Radicals
1. V. Strehmel, "Selection of Ionic Liquids for Free Radical Polymerization Processes", Macromol. Symp. 2007, 254, 25-33.
2. V. Strehmel, Hans Rexhausen, P. Strauch, “Synthesis of 4-sulfonatooxy-2,2,6,6-tetramethylpiperidine-1-yloxyl derivatives for investigation of ionic liquids”, Tetrahedron Letters, 49(2008), 586-588.
3. Veronika Strehmel, Hans Rexhausen, Peter Strauch, "Synthesis of 4-trimethylammonio-2,2,6,6-tetramethylpiperidine-1-yloxyl with various anions for investigation of ionic liquids", Tetrahedron Letters, 49 (2008), 3264-3267.
4. V. Strehmel, H. Rexhausen, P. Strauch, E. Gçrnitz, and B. Strehmel, "Temperature Dependence of Interactions between Stable Piperidine-1-yloxyl Derivatives and an Ionic Liquid", ChemPhysChem, 9 (2008), 1294-1302.
5. V. Strehmel, H. Rexhausen, P. Strauch,"Synthesis of a new ionic spin probe for investigation for polar and nonpolar solvents", Tetrahedron Letters, 49 (2008), 7143-7145.
6. Veronika Strehmel, James F. Wishart, Dmitry E. Polyansky, and Bernd
Strehmel, "Recombination of Photogenerated Lophyl Radicals in
Imidazolium-Based Ionic Liquids", ChemPhysChem, 10 (2009), 3112-3118.
7. Veronika Strehmel, Hans Rexhausen, and Peter Strauch, "Influence of imidazolium bis(trifluoromethylsulfonylimide)s on the rotation of spin
probes comprising ionic and hydrogen bonding groups", Phys. Chem. Chem.
Phys., 12 (2010), 1933-1940.
8. Veronika Strehmel, Hans Rexhausen, and Peter Strauch,
"2,2,6,6-Tetramethylpiperidine-1-yloxyl bound to the imidazolium ion by
an acetamido group for investigation of ionic liquids", Tetrahedron
Letters, 51 (2010), 747-750.
9. Ralf Lungwitz, Veronika Strehmel, and Stefan Spange, "The
dipolarity/polarizability of 1-alkyl-3-methylimidazolium ionic liquids
as function of anion structure and the alkyl chain length", New J.
Chem., 34 (2010), 1135-1140.
10. Veronika Strehmel, Hans Rexhausen, Peter Strauch, and Bernd
Strehmel, "Temperature Dependence of Interactions Between Stable
Piperidine-1-yloxyl Derivatives and a Semicrystalline Ionic Liquid",
ChemPhysChem (2010), DOI: 10.1002/cphc.200900977.
11. Veronika Strehmel, Ralf Lungwitz, Hans Rexhausen, and Stefan Spange,
"Relationship between hyperfine coupling constants of spin probes and
empirical polarity parameters of some ionic liquids", New J. Chem.
(2010), DOI: 10.1039/c0nj00253d.
Jörg Sundermeyer, Philipps-Universität Marburg
Project: Design of Catalytic Ionic Liquids for Oxidation Catalysis
Papers and patents:
1. Th. Linder, J. Sundermeyer, „Hydrophobe Ionische Flüssigkeiten“, DE 10 2006 023 649 A1.
2. Th. Linder, J. Sundermeyer, “Hydrophobic Ionic Liquids”, WO 2007/131498 A2.
3. T. Frömling, M. Kunze, M. Schönhoff, J. Sundermeyer, B. Roling, “Enhanced lithium transference numbers in ionic liquid electrolytes”, J. Phys. Chem. B 2008,112, 12985-12990.
4. Th. Linder, “Pentafluorphenylamide - Von interessanten Liganden in der Seltenerdmetallchemie zu neuen Anionen in ionischen Flüssigkeiten”, doctoral thesis 2008, Marburg.
5. Th. Linder, J. Sundermeyer, “Three novel anions based on pentafluorophenyl amine combined with two new synthetic strategies for the synthesis of highly lipophilic ionic liquids”, Chem. Commun. 2009, 2914-2916.
6. J. Sundermeyer, B. Roling, T. Linder, T. Frömling, B. Huber, “Neue Pentafluorphenylamidoanionen umfassende Lithiumsalze, ihre Herstellung und ihre Verwendung”, EP 09173567.0, (priority 20.10.2009).
7. M. Stricker, Th. Linder, B. Oelkers, J. Sundermeyer, “Cu(I)/(II) based catalytic ionic liquids, their metallo-laminate solid state structures and catalytic activities in oxidative methanol carbonylation”, Green Chem. 2010, DOI: 10.1039/c003948a.
8. J. Sundermeyer, B. Oelkers, “Hexaorganoguanidinium-organocarbonate, ihre Herstellung und ihre Verwendung“, European Patent Appl. EP 10152769.5 (priority 05.02.2010).
9. R. Lungwitz, Th. Linder, J. Sundermeyer, I. Tkatchenko, S. Spange, “Synthesis of chemisorbed imidazolium and phosphonium cations by reaction of ionic liquid precursors with silica”, Chem. Commun. 2010, submitted.
10. B. Oelkers, J. Sundermeyer, “Pentaalkylmethylguanidinium methylcarbonates via solvent-free synthesis - versatile precursors for the preparation of halide-free guanidinium-based ILs (GILs)”, Chem. Commun. 2010, submitted.
Lectures and poster contributions:
1. T. Linder, J. Sundermeyer, “New hydrophobic ionic liquids based on Pentafluorophenylimides”, Symposium des DFG SPP 1191, Bamberg, 30.04. -01.05.2007. (oral presentation)
2. T. Linder, M. Stricker, J. Sundermeyer, “Design of Catalytic Ionic Liquids for Oxidation Catalysis”, Symposium des DFG SPP 1191, Bamberg, 30.04.2007 - 01.05.2007. (poster contribution)
3. T. Linder, J. Sundermeyer, „Neue hydrophobe ionische Flüssigkeiten auf Basis von Pentafluorphenylimiden“, GDCh Wissenschaftsforum 2007, Ulm, 16.09.2007 - 19.09.2007. (poster contribution)
4. M. Stricker, J. Sundermeyer, “Catalytic ionic liquids (CILs) of group 11 - application in the synthesis of dimethyl carbonate”, Jahrestreffen des DFG SPP 1191, Bamberg, 12.12.2007 - 14.12.2007. (oral presentation)
5. T. Linder, J. Sundermeyer, “New hydrophobic ionic liquids based on pentafluorophenylimido anions”, Jahrestreffen des DFG SPP 1191, Bamberg, 12.12.2007 - 14.12.2007. (poster contribution)
6. M. Stricker, T. Linder, J. Sundermeyer, “Catalytic ionic liquids (CILs) of group 11 and hydrophobic ILs based on pentafluorophenylimides – methods of characterization and application”, winterschool of the DFG SPP 1191, Leipzig, 19.02. - 22.02.2008. (oral presentation)
7. J. Sundermeyer, “Reductive Oxygen Activation at Cu(I) and Oxidative Substrate Activation at Cu(II): Two Ways of Selective Catalytic Oxygenations with Molecular Oxygen”, ETH Zürich, Annual Symposium on Inorganic Chemistry 2008, 12.03.2008. (oral presentation)
8. J. Sundermeyer, “Design of Task Specific Ionic Liquids for Oxidation Catalysis, Gas Chemisorption and Electrochemical Devices”, BASF, Ludwigshafen, 21.08.2008. (oral presentation)
9. J. Sundermeyer, “Copper containing catalytic ionic liquids in selective oxygenations with dioxygen”, Friedrichshafen, DECHEMA Tagung “Green Solvents”, 28.09. - 01.10.2008. (oral presentation)
10. M. Stricker, J. Sundermeyer, “Copper Based Catalytic Ionic Liquids (CILs) in the Synthesis of Dimethyl Carbonate (DMC)”, Green Solvents 2008, Friedrichshafen, 28.09. - 01.10.2008, poster award (first place). (poster contribution)
11. B. Oelkers, J. Sundermeyer, “Sulfonated Aza Ligands for the Immobilization of Group 10 Metal Complexes in Catalytic ILs (CILs)”, DFG SPP 1191 meeting, Bamberg, 04.03. - 06.03.2009. (poster contribution)
12. M. Stricker, J. Sundermeyer, “Copper and Cobalt Based Ionic Liquids as Oxidation Catalysts and/or Gas Carriers”, DFG SPP 1191 meeting, Bamberg, 04.03. - 06.03.2009. (poster contribution)
13. M. Stricker, J. Sundermeyer, “Copper Based Ionic Liquids as Oxidation Catalysts”, COIL-3, Cairns Australia, 31.05. - 04.06.2009. (poster contribution)
14. J. Sundermeyer, M. Stricker, H. Sun, “Copper Containing Catalytic Ionic Liquids (CIL) in Selective Oxygenations with Dioxygen”, COIL-3, Cairns Australia, 31.05. - 04.06.2009. (poster contribution)
15. T. Linder, J. Sundermeyer, “New Hydrophobic Ionic Liquids Based on Pentafluorophenylimido Anions”, COIL-3, Cairns Australia, 31.05. - 04.06.2009. (poster contribution)
16. J. Sundermeyer, “Design of Task-Specific Ionic Liquids for Oxidation Catalysis, Gas Chemisorption and Electrochemical Devices”, Merck Darmstadt, 18.06.2009. (oral presentation)
17. B. Oelkers, J. Sundermeyer, “Sulfonated Diazadiene Ligands (DADs) for the Immobilization of Metal Complexes in ILs”, annual meeting of the DFG SPP 1191, Potsdam, 04.11. - 06.11.2009. (oral presentation)
18. B. Oelkers, J. Sundermeyer, “Sulfonated Diazadiene Ligands (DADs) for the Immobilization of Metal Complexes in Ionic Liquids (ILs)”, annual meeting of the DFG SPP 1191, Potsdam, 04.11. - 06.11.2009. (poster contribution)
19. M. Stricker, J. Sundermeyer, “Copper Based Ionic Liquids - Oxidation Catalysis, Gas Absorption and Mechanistic Studies”, annual meeting of the DFG SPP 1191, Potsdam, 04.11. - 06.11.2009. (poster contribution)
20. J. Sundermeyer, M. Stricker, H. Sun, “Copper based catalytic ionic liquids - synthesis, characterization and application”, EUCHEM 2010, Bamberg, 14.03. - 19.03.2010. (oral presentation)
21. B. Oelkers, J. Sundermeyer, “Sulfonated Diazadiene Ligands (DADs) for the Immobilization of Metal Complexes in Ionic Liquids (ILs)”, EUCHEM 2010, Bamberg, 14.03. - 19.03.2010. (poster contribution)
22. M. Stricker, H. Sun, J. Sundermeyer, “Coinage Metal Based Catalytic Ionic Liquids – Synthesis, Characterisation and Application”, EUCHEM 2010, Bamberg, 14.03. - 19.03.2010. (poster contribution)
23. R. Lungwitz, S. Spange, TU Chemnitz; T. Linder, J. Sundermeyer, University of Marburg, “Physi- and chemisorption of ionic liquids onto inorganic solid catalysts”, EUCHEM 2010, Bamberg, 14.03. - 19.03.2010. (poster contribution)
24. J. Sundermeyer, “Privileged Ligands in Lewis Acids and Redox Catalysts for the Conversion of Dioxygen, Carbon Monoxide, Amines and Olefins to Commodity Chemicals”, Leibniz-Institut für Katalyseforschung, Rostock, 17.05.2010. (oral presentation)
25. J. Sundermeyer, “Activation and Redox Reactivity of Dioxygen and Other Oxidants at Copper and Cobalt Complexes: From Fundamental to Applied Chemisty”, Canadian Chemical Society Annual Meeting, Toronto, 01.06.2010, invited lecture.
Jorg Thoeming, Universitaet Bremen
Project: The contribution of different molecular interaction
potentials to the chemical potential of ionic liquid ions in various
chemical environments
1. Jastorff B, Mölter K, Behrend P, Bottin-Weber U, Filser J, Heimers A, Ondruschka B, Ranke J, Schaefer M, Schröder H, Slenzka K, Stark A, Stepnowski P, Stock F, Störmann R, Stolte S, Welz-Biermann U, Ziegert S, Thöming J (2005). Strategy in evaluation of risk potential of ionic liquids – basis for an eco-design of sustainable products. Green Chemistry, 7, 362–372.
2. Waterkamp D, Heiland M, Schlüter M, Sauvageau, JC, Beyersdorff T, Thöming J (2007). Synthesis of Ionic Liquids in Micro-Reactors – A Process Intensification Study. Green Chemistry, 9, 1084 – 1090.
3. Jungnickel C, Luczak J, Ranke J, Fernández JF, Müller A and Thöming J (2007). Aggregate formation of imidazolium ionic liquids in aqueous solution. Proceedings SURUZ 2007: Surfactants and Dispersed Systems in Theory and Practice, 153-156.
4. Fernández JF, Waterkamp D and Thöming J (2007). Recovery of Ionic Liquids from Wastewater: Aggregation Control for Intesified Membrane Filtration. Proceedings 11th Aachener Membran Kolloquium, 391-396.
5. Fernández JF, Waterkamp DA, Thoming J (2008). Recovery of ionic liquids from wastewater: Aggregation control for intensified membrane filtration. Desalination 224, 52-56.
6. Jungnickel C, Luczak J, Fernández JF, Ranke J, Müller A, Thöming J (2008). Micelle formation of imidazolium ionic liquids in aqueous solution. Colloids and Surfaces A: Physicochem. Eng. Aspects, 316 (1), 278-284.
7. Stolte S, Abdulkarim S, Arning J, Blomeyer-Nienstedt AK, Bottin-Weber U, Matzke M, Ranke J, Jastorff B, Thöming J (2008). Primary biodegradation of ionic liquid cations, identification of degradation products of 1-methyl-3-octyl -imidazolium chloride and electrochemical waste water treatment of poorly biodegradable compounds. Green Chem. 10, 214–224.
8. Fernández JF, Chilyumova E, Waterkamp DA and Thöming J (2008). Ionic liquid recovery from aqueous solutions by cross-flow nanofiltration. Proceedings 10th World Filtration Congress, Volume II, 528-532.
9. Thöming J, Waterkamp DA (2008). Towards Regeneration and Re-use of Ionic Liquids in Electroplating. In: Electrodeposition in Ionic Liquids, ed. Frank Endres, Andrew Abbott und Douglas MacFarlane, Wiley-VCH, 312-319.
10. Jungnickel C, Thöming J, Preiss U, ?uczak J, and Krossing I (2008). A method to predict the critical micelle concentration of ionic liquids from the molecular volume. Oils & Fuels for Sustainable Development, J. Hupka, A. Tonderski, R. Aranowski and C. Jungnickel, Gdansk, Gdansk University of Technology, 243-249.
11. Luczak J, Hupka J, Thöming J, and Jungnickel C (2008). Self-organization of imidazolium ionic liquids in aqueous solution. Colloids and Surfaces A: Physicochem. Eng. Aspects, Colloids and Surfaces A: Physicochem. and Eng. Aspects 329, 125-133.
12. Waterkamp DA, Thöming J (2008). Farblose ionische Flüssigkeit und Verfahren zu ihrer Herstellung. DP 10 2008 041 491.3-44.
13. Luczak J, Jungnickel C, Joskowska M, Thöming J, and Hupka J (2009). Thermodynamics of micellization of imidazolium ionic liquids in an aqueous solution. Journal of Colloid and Interface Science 336, 111-116.
14. Preiss U, Jungnickel C, Thöming J, Krossing I, ?uczak J, Diedenhofen M, and Klamt A (2009). Predicting the Critical Micelle Concentration of Ionic Liquids and other Ionic Surfactants. Chemistry - A European Journal 15 (35), 8880-8885.
15. Waterkamp DA, Engelbert M, Thöming J. (2009). On the Effect of Enhanced Mass Transfer on Side Reactions in Capillary Microreactors during High-Temperature Synthesis of an Ionic Liquid. Chem. Eng. Technol. 32 (11), 17171723.
16. Neumann J; Grundmann O; Thöming J; Schulte M; Stolte S (2010). Anaerobic
biodegradability of ionic liquid cations under denitrifying conditions, Green Chemistry 12, 620-627.
Andreas-Neil Unterreiner, Universität Karlsruhe (Technische Hochschule)
Project: Ultrafast relaxation dynamics of ionic liquids using solvated electrons as a probe
1. J. Lindner, A.-N. Unterreiner, and P. Vöhringer, “Femtosecond Relaxation Dynamics of Solvated Electrons in Liquid Ammonia”, Chem. Phys. Chem., 7,
363-369 (2006).
2. N. Chandrasekhar, F. Endres and A.-N. Unterreiner, “Ultrafast dynamics of
excess electrons in molten salts: Part III. Formation of solvated electrons in room temperature ionic liquids”, Phys. Chem. Chem. Phys., 8, 3192-3196 (2006).
3. N. Chandrasekhar and A.-N. Unterreiner, “Relaxation Dynamics upon Ultrashort UV Photo-Excitation of an Iodide Doped Ionic Liquid and of a Pure Lithium Iodide Melt”, Z. Phys. Chem., 220, 1235-1246 (2006).
4. N. Chandrasekhar, P. Krebs, and A.-N. Unterreiner, “One-photon photodetachment of I- in glycerol: spectra and yield of solvated electrons in the temperature range 329 £ T £ 536 K”, J. Chem. Phys., 125, 164512-1-164512-7 (2006).
5. H. Brands, N. Chandrasekhar and A.-N. Unterreiner, “Ultrafast Dynamics of Room Temperature Ionic Liquids after UV-Femtosecond Excitation”, J. Phys. Chem. B, 111 (18), 4830-4836 (2007).
6. N. Chandrasekhar, A.-N. Unterreiner, “Time-resolved polaron dynamics in molten solutions of cesium-doped cesium iodide”, J. Chem. Phys. 127,
184508-1 – 184508-6 (2007).
Rudi van Eldik, Friedrich-Alexander-Universität Erlangen-Nürnberg
Project: Experimental and theoretical studies on the mechanistic behaviour of catalytic-relevant metal complexes in ionic liquids
1. P. Illner, S. Kern, S. Begel and R. van Eldik, "Rapid ligand substitution reactionsin ionic liquids studied by stopped-flow technique", Chem. Commun., 4803-4805 (2007)
2. T.D. Dolidze, D.E. Khoshtariya, P. Illner, L. Kulisiewicz, A. Delgado and
R. van Eldik, "High-pressure testing of heterogeneous charge transfer in a
room-temperature ionic liquid: Evidence for solvent dynamic control",
J. Phys. Chem. B, 112, 3085-3100 (2008)
3. T.D. Dolidze, D.E. Koshtariya, P. Illner and R. van Eldik, "Heterogeneous
electron transfer at Au/SAM junctions in a room-temperature ionic liquid under pressure", Chem. Commun., 2112-2114 (2008)
4. S. Begel, P. Illner, S. Kern, R. Puchta ands R. van Eldik, "Mechanistic studies on fast ligand substitution reactions of Pt(II) in different ionic liquids. Role of solvent polarity and ion-pair formation", Inorg. Chem. 7121-7132 (2008)
5. P. Illner, S. Begel, S. Kern, R. Puchta, R. van Eldik, „Fast Substitution
Reactions of Pt(II) in Different Ionic Liquids. Reactivity Control by Anionic
Components.” Inorg. Chem. 588-597 (2009)
6. M. Schmeisser, R. van Eldik, “Thermodynamic and kinetic studies on reactions of Fe(III)(meso-[tetra(3-sulfonatomesityl)porphin]) with NO in an ionic liquid. Trace impurities can change the mechanism!” Inorg. Chem. 7466-75 (2009)
7. S. Kern, P. Illner, S. Begel, R. van Eldik, “Mechanistic studies on fast ligand substitution reactions of a very labile Pd(II) complex in several ionic liquids” Eur. J. Inorg. Chem. accepted.
Peter Wasserscheid, Friedrich-Alexander-Universität Erlangen-Nürnberg
Project 1: Ionic liquid surface science
1. F. Maier, J. M. Gottfried, J. Rossa, D. Gerhard, P. S. Schulz, W. Schwieger, P. Wasserscheid, H.-P. Steinrück, “Surface Enrichment and Depletion Effects of Ions Dissolved in Ionic Liquids: An X-ray Photoelectron Spectroscopy Study“, Angew. Chem. 2006, 118, 7942-7944; Angew. Chem., Int. Ed. 2006, 45(46), 7778-7780.
2. J. M. Gottfried, F. Maier, J. Rossa, D. Gerhard, P. S. Schulz, P. Wasserscheid, H.-P. Steinrück, “Surface Studies on the Ionic Liquid 1-Ethyl-3-methylimidazo-lium Ethylsulfate Using X-Ray Phtoelectron Spectroscopy (XPS)”, Z. Phys. Chem. 2006, 220, 1439-1453.
3. N. Paape, W. Wei, A. Bösmann, C. Kolbeck, F. Maier, H.-P. Steinrück, P. Wasserscheid, and P.S. Schulz, "Chloroalkylsulfonate ionic liquids by ring opening of sultones with organic chloride salts", Chem. Comm. 2008, 33, 3867.
4. C. Kolbeck, M. Killian, F. Maier, N. Paape, P. Wasserscheid, and H.-P. Steinrück, "Surface characterization of functionalized imidazolium-based ionic liquids", Langmuir 2008, 24, 9500.
5. T. Cremer, M. Killian, J.M. Gottfried, N. Paape, P. Wasserscheid, F. Maier, H.-P. Steinrück, "Physical vapor deposition of [EMIM][Tf2N]: A new approach to the modification of surface properties with ultrathin ionic liquid films", ChemPhysChem 2008, 9, 2185.
6. K. Lovelock, C. Kolbeck, T. Cremer, N. Paape, P. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, "The influence of different substituents on the surface composition of ionic liquids studied using ARXPS, J. Phys. Chem. B, 2009, 113, 2854.
7. C. Kolbeck, K. R. J. Lovelock, T. Cremer, N. Paape, P. Wasserscheid, F. Maier, H.-P. Steinrück, “Influence of Different Anions on the Surface Composition of Ionic Liquids Studied Using ARXPS”, J. Phys. Chem. B 113 (2009) 8682-8688.
8. F. Maier, T. Cremer, C. Kolbeck, K.R.J. Lovelock, N. Paape, P.S. Schulz, P. Wasserscheid, H.-P. Steinrück, ”Insights into surface composition and enrichment effects of ionic liquids and ionic liquid mixtures”, Phys. Chem. Chem. Phys. 12 (2010) 1905-1915, invited contribution.
9. M. Sobota, I. Nikiforidis, W. Hieringer, N. Paape, M. Happel, H.-P. Steinrück, A. Görling, P. Wasserscheid, M. Laurin, J. Libuda, “Towards Ionic Liquid Based Model Catalysis: Growth, Orientation, Conformation and Interaction Mechanism of [BMIM][Tf2N] Thin Films on an Ordered Alumina Surface”, Langmuir 26 (2010) 7199-7207.
10. T. Cremer, C. Kolbeck, K. R. J. Lovelock, N. Paape, P. S. Schulz, P. Wasserscheid, H. Weber, J. Thar, B. Kirchner, R. Wölfel, F. Maier and H.-P.-Steinrück, ”Towards a Molecular Understanding of Cation-Anion Interactions - Probing the Electronic Structure of Imidazolium Ionic Liquids by XPS, NMR and Theory”, Chemistry – A European Journal (accepted)
Project 2: Chirality transfer in ionic liquids via ion pairing effects
1. S.J. Sachnov. K. Schneiders, P.S. Schulz. P. Wasserscheid „Chirality Transfer in Mandelate Ionic Liquids Through Ion Pairing Effects” Tetrahedron: Assymetry, 2010, in press.
2. P.S. Schulz, K. Schneiders, P. Wasserscheid „ Aggregation Behaviour of Chiral Ionic Liquids”, Tetrahedron: Asymmetry, 2009, 20, 2479-2481.
3. K. Schneiders, P.S. Schulz, M. Kamm, B. Kamm, P. Wasserscheid „Biobased chiral platform chemical carnitine - derived ionic liquids”, ChemSusChem, submitted.
4. K. Schneiders, A. Bösmann, P.S. Schulz, P. Wasserscheid, “Chirality transfer in imidazolium camphorsulfonate ionic liquids through ion pairing effects”', Adv. Synth. Catal. 351, 2009, 432-440.
5. N. Müller, P.S. Schulz, A. Bösmann, P. Wasserscheid, “Effective Chirality Transfer in Ionic Liquids Through Ion-Pairing Effects”, Angew. Chem., Int. Ed. 46(8), 2007, 1293-1295.
6. A. Bösmann, P.S. Schulz, P. Wasserscheid, “Enhancing Task Specific Ionic Liquids' Thermal Stability by Structural Modification”, Monatshefte für Chemie, 2007, 138(11), 1159-1161.
7. K. Schneiders, V.Wagner, S. J. Sachnov, P. S. Schulz, P. Wasserscheid “Influence of structural parameters on ion-pairing effects” (Euchem 2010, Bamberg, March 2010)
8. P.S. Schulz “NMR-Spectroscopy as a tool for Investigation of Ionic Liquids' properties” Talk (ISHHC XIV, Stockholm, September 2009)
9. P.S. Schulz, K, Schneiders, P. Wasserscheid “NMR-Spectroscopy as a tool for investigation of Ionic Liquids properties” Poster (EuropaCat IX, Salamanca, August 2009).
10. K. Schneiders, P. Wasserscheid, P.S. Schulz “Chirality transfer in Ionic Liquids via ion-pairing effects” Poster (COIL, Cairns, May 2009).
11. P.S. Schulz, K, Schneiders, P. Wasserscheid “NMR-Spectroscopy as a tool for investigation of Ionic Liquids properties” Poster (COIL, Cairns, May 2009).
12. K. Schneiders, P. Wasserscheid, P.S. Schulz, Asymmetric “Hydrogenation of Ionic Liquids” Poster (Jahrestagung Deutscher Katalytiker, Weimar, March 2009).
13. P.S. Schulz “Ion Pairing in Ionic Liquids, NMR-Spectroscopy as a tool for Investigation of Ionic Liquids' properties” Talk (International Bunsen Discussion Meeting, November 2008, Clausthal-Zellerfeld).
14. K. Schneiders, P.
Wasserscheid, P.S. Schulz, „Dissociation and Ion-pair formation in Ionic
Liquid Solutions” Poster (Green Solvents, Friedrichshafen, September
2008).
15. K. Schneiders, P. S.
Schulz, P. Wasserscheid “Asymmetric Hydrogenation of Ionic Liquids“
Poster (Jahrestreffen Deutscher Katalytiker, Weimar, 2008).
16. P. S. Schulz, A.
Bösmann, N. Müller, K. Schneiders, P. Wasserscheid “Asymmetric
Hydrogenation of Ionic Liquids” Poster (Conference on Ionic Liquids,
Yokohama, 2007).
Hermann Weingärtner, Ruhr-Universität Bochum
Project: Dielectric spectroscopy of ordering and dynamics of ionic liquids and their mixtures with solvents of low polarity
1．H. Weingärtner, P. Sasisanker, C. Daguenet, P.J. Dyson, I. Krossing, J. M. Slattery, and T. Schubert, “The Dielectric Response of Room-Temperature Ionic Liquids: Effect of Cation Variation”, J. Phys. Chem. B 111, 4775-4780 (2007)
2．A. Wulf, R. Ludwig, P. Sasisanker, H. Weingärtner, “Molecular reorientation in ionic liquids: A comparative dielectric and magnetic relaxation study”, Chem. Phys. Lett. 439, 323-326 (2007)
3．C. Schröder，C. Wakai, H. Weingärtner and O. Steinhauser, “Collective rotational dynamics in ionic liquids: A computational and experimental study of 1-butyl-3-methyl-imidazolium tetrafluoroborate”, J. Chem. Phys. 126, 084511 (2007)
4．H. Weingärtner， “The static Dielectric Constant of Ionic Liquids”, Z. Phys. Chem. 220,1395-1405(2006)
5. Ingo Krossing, John M. Slattery, Corinne Daguenet, Paul J. Dyson, A. Oleinikova, and H. Weingärtner, “Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies”, J. AM. CHEM. SOC., 128, 13427-13434 (2006)
6. H. Weingärtner, “Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies”, Angew. Chem. Int. Ed. 47, 654-670 (2008)
7. Huang M.-M.; Weingärtner, H.; Protic ionic liquids with unusually high
dielectric permittivities, Chem. Phys. Chem., 2008, 9(15), 2172-2173.
8. Krüger, M.; Bründermann, E.; Funkner, S.; Weingärtner, H.; Havenith,
M., Polarity fluctuations of the protic ionic liquid ethylammonium
nitrate in the terahertz regime, J. Chem. Phys, 2010, 132,
101101/1-101101/4.
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